216251-99-9Relevant academic research and scientific papers
Generation of a silylene complex by the 1,2-migration of hydrogen from silicon to platinum
Mitchell, Gregory P.,Tilley, T. Don
, p. 2524 - 2526 (2007/10/03)
An extraordinary downfield-shifted 29Si{1H} NMR signal is seen at δ = 338.5 for the platinum silylene complex [(dippe)(H)Pt=SiMes2][MeB(C6F5)3] (2). This remarkably stable metal silylene complex was obtained from 1 in the first intramolecular 1,2-hydride migration from silicon to a transition metal. dippe = iPr2PCH2CH2PiPr2, Mes = 2,4,6-Me3C6H2.
