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1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 99% [EMIBETI] is an ionic liquid that is characterized by its high purity and unique chemical properties. It is composed of a 1-ethyl-3-methylimidazolium cation and a bis(pentafluoroethylsulfonyl)imide anion, which contribute to its excellent thermal stability, low volatility, and high ionic conductivity.

216299-76-2

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216299-76-2 Usage

Uses

Used in Chemical Research:
1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 99% [EMIBETI] is used as a model ionic liquid for the preparation of supported ionic liquid membranes (SILMs). These membranes are employed in the studies of CO2 and N2 gas permeation, providing insights into the separation and purification of gases.
Used in Solubility and Absorption Studies:
1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 99% [EMIBETI] is used as a medium for the studies of solubility and absorption of 1,1,1,2-tetrafluoroethane, difluoromethane, and fluorinated ethanes in ionic liquids. This helps in understanding the interactions between ionic liquids and various gases, which is crucial for the development of efficient gas separation and absorption processes.
Used in Electro-polymerization Processes:
1-Ethyl-3-methylimidazolium bis(pentafluoroethylsulfonyl)imide, 99% [EMIBETI] is used as a medium for the electro-polymerization of pyrrole-based monomers. This process yields N-(methyl)phenyl polypyrroles, which have potential applications in various fields such as sensors, batteries, and fuel cells. The use of EMIBETI as a medium allows for better control over the polymerization process and improved properties of the resulting polymers.

Check Digit Verification of cas no

The CAS Registry Mumber 216299-76-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,1,6,2,9 and 9 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 216299-76:
(8*2)+(7*1)+(6*6)+(5*2)+(4*9)+(3*9)+(2*7)+(1*6)=152
152 % 10 = 2
So 216299-76-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H11N2.C4F10NO4S2/c1-3-8-5-4-7(2)6-8;5-1(6,7)3(11,12)20(16,17)15-21(18,19)4(13,14)2(8,9)10/h4-6H,3H2,1-2H3;/q+1;-1

216299-76-2 Well-known Company Product Price

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  • Aldrich

  • (39056)  1-Ethyl-3-methylimidazoliumbis(pentafluoroethylsulfonyl)imide  ≥97.0% (H-NMR)

  • 216299-76-2

  • 39056-1G-F

  • 3,875.04CNY

  • Detail
  • Aldrich

  • (39056)  1-Ethyl-3-methylimidazoliumbis(pentafluoroethylsulfonyl)imide  ≥97.0% (H-NMR)

  • 216299-76-2

  • 39056-5G-F

  • 14,964.30CNY

  • Detail

216299-76-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide,1-ethyl-3-methylimidazol-3-ium

1.2 Other means of identification

Product number -
Other names EMIMBeTi

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:216299-76-2 SDS

216299-76-2Downstream Products

216299-76-2Relevant academic research and scientific papers

Exploring the effect of fluorinated anions on the CO2/N2 separation of supported ionic liquid membranes

Gouveia, Andreia S. L.,Tomé, Liliana C.,Lozinskaya, Elena I.,Shaplov, Alexander S.,Vygodskii, Yakov S.,Marrucho, Isabel M.

, p. 28876 - 28884 (2017)

The CO2 and N2 permeation properties of ionic liquids (ILs) based on the 1-ethyl-3-methylimidazolium cation ([C2mim]+) and different fluorinated anions, namely 2,2,2-trifluoromethylsulfonyl-N-cyanoamide ([TFSAM]-), bis(fluorosulfonyl) imide ([FSI]-), nonafluorobutanesulfonate ([C4F9SO3]-), tris(pentafluoroethyl)trifluorophosphate ([FAP]-), and bis(pentafluoroethylsulfonyl)imide ([BETI]-) anions, were measured using supported ionic liquid membranes (SILMs). The results show that pure ILs containing [TFSAM]- and [FSI]- anions present the highest CO2 permeabilities, 753 and 843 Barrer, as well as the greatest CO2/N2 permselectivities of 43.9 and 46.1, respectively, with CO2/N2 separation performances on top of or above the Robeson 2008 upper bound. The re-design of the [TFSAM]- anion by structural unfolding was investigated through the use of IL mixtures. The gas transport and CO2/N2 separation properties through a pure [C2mim][TFSAM] SILM are compared to those of two different binary IL mixtures containing fluorinated and cyano-functionalized groups in the anions. Although the use of IL mixtures is a promising strategy to tailor gas permeation through SILMs, the pure [C2mim][TFSAM] SILM displays higher CO2 permeability, diffusivity and solubility than the selected IL mixtures. Nevertheless, both the prepared mixtures present CO2 separation performances that are on top of or above the Robeson plot.

Dissolution of oligo(tetrafluoroethylene) and preparation of poly(tetrafluoroethylene)-based composites by using fluorinated ionic liquids

Tsurumaki, Akiko,Ohno, Hiroyuki

supporting information, p. 409 - 412 (2018/02/27)

Fluorophilic ionic liquids (ILs) showing enhanced compatibility with poly(tetrafluoroethylene) (PTFE) have been newly synthesised. The as-designed ILs contributed both to the dissolution of PTFE oligomers and to the preparation of composites with PTFE with no fear of bleed-out of the ILs.

FLUORINE-CONTAINING N-ALKYLSULFONYLIMIDE COMPOUND, MANUFACTURING METHOD THEREFOR, AND METHOD OF MANUFACTURING AN IONIC COMPOUND

-

Page/Page column 7, (2012/02/03)

According to the method for producing fluorine-containing N-alkylsulfonylimide compound, the fluorine-containing N-alkylsulfonylimide compound can be produced safely with a high recovery rate by alkylating fluorine-containing sulfonylimide acid or fluorine-containing sulfonylimide acid salt with dialkylsulfuric acid or dialkylcarbonic acid.

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