21655-75-4Relevant academic research and scientific papers
Kinetic and quantum chemical studies of the mechanism of dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite ions
Kazin,Kuzhin,Sirik,Guzov
, p. 1277 - 1281 (2016/10/26)
The E2 mechanism has been proposed for the dehydrochlorination of 2,2-diaryl-1,1,1-trichloroethanes with nitrite ion, leading to 2,2-diaryl-1,1-dichloroethenes, on the basis of experimental kinetic study and quantum chemical simulation.
Kinetics and mechanism of the dehydrohalogenation of Ar2CHCX3 and Ar2CHCHX2 by strong N-bases
Schroeder, Grzegorz,Leska, Boguslawa,Gierczyk, Blazej,Bartosz Rozalski,Brzezinski, Bogumil
, p. 173 - 179 (2007/10/03)
The kinetics and mechanism of the elimination reactions of 1,1,1- trifluoro-, 1,1,1-trichloro-, 1,1,1-tribromo-, 1,1-dichloro- and 1,1-dibromo- 2,2-bis(4-nitrophenyl)ethanes and two strong N-bases: 1,5,7- triazabicyclo[4.4.0]dec-5-ene (TBD) and 7-methyl-1
KINETICS AND ISOTOPE EFFECTS OF THE DEHYDROCHLORINATION OF 1,1,1-TRICHLORO-2,2-BIS-(4-NITROPHENYL)ETHANE WITH PIPERIDINE, PYRROLIDINE AND QUINUCLIDINE IN ACETONITRILE SOLVENT
Dworniczak, Miroslaw,Jarczewski, Arnold
, p. 123 - 128 (2007/10/02)
Rate constants for the β-elimination reaction of HCl from 1,1,1-trichloro-2,2-bis-(4-nitrophenyl)ethane (I) promoted by piperidine, pyrrolidine, and quinuclidine bases in acetonitrile have been measured.Activation parameters are characterized by moderate
KINETICS, ISOTOPE EFFECTS AND MECHANISM OF THE REACTION OF SOME DINITROPHENYLETHANES WITH SODIUM PROPANETHIOLATE IN PROPANOL
Schroeder, Grzegorz
, p. 565 - 576 (2007/10/02)
The reaction between Ar2CHCF3, Ar2CHCCl3, Ar2CHCHCl2 (where Ar=O2NC6H4) and sodium propanethiolate in propanol has been investigated.The reaction of Ar2CHCF3 with sodium propanethiolate gave the following alkenes: Ar2C=CF2, Ar2C=CF(SPr) and Ar2C=C(SPr)2,
Kinetics and isotope effects of the β-elimination reactions of some 2,2-di(4-nitrophenyl)chloroethanes promoted by tetramethylguanidine in aprotic solvents
Jarczewski, Arnold,Waligorska, Malgorzata,Leffek, Kenneth T.
, p. 1194 - 1197 (2007/10/02)
Rate constants for the β-elimination of HCl from 2,2-di(4-nitrophenyl)-1,1-dichloroethane (I) and 2,2-di(4-nitrophenyl)-1,1,1-trichloroethane (II) promoted by tetramethylguanidine in the aprotic solvents acetonitrile, tetrahydrofuran, and n-hexane have be
