216862-40-7

Upstream product

• 25320-59-6 tetra-O-benzyl glucopyranosyl chloride 
• 15038-71-8 methyl 2-O-benzyl-(R)-4,6-O-benzylidene-α-D-mannopyranoside 
• 38184-10-0 phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 216758-62-2 methyl-4,6-O-benzylidene-3-O-(p-methoxybenzyl)-α-D-mannopyranoside 
• 216758-63-3 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-p-methoxybenzyl-α-D-mannopyranoside 
• 132201-75-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate 
• 132748-02-8 O-(2,3,4,6-tetra-O-benzyl-α,β-D-galactopyranosyl)trichloroacetimidate 
• 3162-96-7 methyl-4,6-O-phenylmethylene-α-D-mannopyranoside 

Relevant academic research and scientific papers

Glycosylation catalyzed by a chiral bronsted acid

"Chemical equation presented" The use of a chiral Bronsted acid catalyst for the activation of trichloroacetimidate glycosyl donors has been demonstrated for the first time. In toluene the chirality of the acid catalyst is seen to influence the stereochem

Stereoselective synthesis of α-glucosides by neighbouring group participation via an intermediate thiophenium ion

The use of a 2-O-(thiophen-2-yl)methyl protecting group allows highly stereoselective α-glucosylation of a trichloroacetimidate donor; increased stereoselectivity, presumably arising from the intramolecular formation of a transient intermediate thiophenium ion, correlates with increased bulk of the glycosyl acceptor.

N-Iodosaccharin: A potent new activator of thiophenylglycosides

N-Iodosaccharin is found to be a potent activator of armed thiophenyl glycosides.

A synthetic approach to the glycan chain of high mannose type N-glycoprotein

The syntheses of α-D-glucopyranose-(1→3)-D-mannopyranose, methyl α-D-glucopyranose-(1→3)-α-D-mannopyranoside and methyl α-D-glucopyranose-(1→3)-α-D-mannopyranose-(1→2)-α-D- mannopyranoside are reported. High stereoselectivity was observed during the coupl