21711-65-9

Usage

Safety Profile

Questionable carcinogen withexperimental tumorigenic data. Mutation data reported.When heated to decomposition it emits toxic fumes ofNOx.

InChI:InChI=1/C10H7NO/c12-11-10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

Upstream product

• 607-51-2 di-[1]naphthyl-mercury 
• 1802-41-1 1-chloromercurionaphthalene 
• 60-29-7 diethyl ether 
• 607-30-7 hydroxynaphthylamine 
• 7758-99-8 copper(II) sulfate 
• 134-32-7 1-amino-naphthalene 

Downstream Products

• 84-86-6 4-amino-1-naphthalenesufonic acid 
• 24344-19-2 1-naphthylsulfamic acid 
• 117505-21-2 C₁₁H₇N₃O 

Relevant academic research and scientific papers

Rhodium(III)-catalyzed regioselective C–H nitrosation/annulation of unsymmetrical azobenzenes to synthesize benzotriazole N-oxides via a RhIII/RhIII redox-neutral pathway

A Rh(III)-catalyzed regioselective C–H nitrosation/annulation reaction of unsymmetrical azobenzenes with [NO][BF4] has been developed to achieve high-yielding syntheses of benzotriazole N-oxides with excellent functional group tolerance. Computational studies have revealed that this oxidative C–H functionalization reaction involves an interesting redox-neutral Rh(III)/Rh(III) pathway without the change of Rh oxidation state.

Tungsten- and molybdenum-based coordination polymer-catalyzed N-oxidation of primary aromatic amines with aqueous hydrogen peroxide

Recyclable tungsten- and molybdenum-based coordination polymers efficiently catalyzed the oxidation of primary aromatic amines to the corresponding nitroso derivatives with 30% aqueous hydrogen peroxide in high yields at room temperature.

Nitroso Compounds by Reaction of Organomercurials with Nitrosyl Chloride

By the reaction of RHgX (X = Cl, Br, OAc) with NOCl, mercury is eliminated as ClHgX and, if R is aromatic, nitroso compounds are obtained, i.e., nitrosobenzene, 1-nitrosonaphthalene, 4-nitroso-N,N-dimethylaniline, 2-nitrosophenol, 4-nitrosophenol and methyl 3-nitrososalicylate. If R is aliphatic or alicyclic, with RHgX to NOCl 1:3, gem-chloronitroso compounds are obtained that have not been described previously, i.e., 2-chloro-2-nitrosocyclohexanol, 1-acetoxy-2-chloro-2-nitrosocyclohexane, 1-chloro-2-methoxy-1-nitrosocyclopentane, methyl 2-chloro-2-nitroso-3-methoxypropionate, 1-chloro-1-nitroso-ethane and 2-chloro-2-nitrosoethanol. All products have been characterized by chemical and IR spectral analysis.