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feed grade copper sulphate 99.5%
Cas No: 7758-99-8
USD $ 3000.0-3000.0 / Metric Ton 1 Metric Ton 1000 Metric Ton/Day Liaoning Chihong Technology Co., Ltd. Contact Supplier
factory supply Copper sulphate with high purity
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Crystal Copper Sulphate CAS NO.7758-99-8 CuSo4
Cas No: 7758-99-8
USD $ 1800.0-2000.0 / Metric Ton 10 Metric Ton 50 Metric Ton/Day VD BIOTECH LIMITED Contact Supplier
Copper sulfate pentahydrate
Cas No: 7758-99-8
No Data 1000 Kilogram 1000 Kilogram/Month Shandong Xinhua Pharmaceutical Co.,Ltd Contact Supplier
High quality Copper(Ii)Sulfatepentahydrate supplier in China
Cas No: 7758-99-8
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Copper Sulphate 7758-99-8
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Food grade Copper sulfate pentahydrate CAS 7758-99-8 with low price
Cas No: 7758-99-8
USD $ 3.0-3.5 / Kilogram 100 Kilogram 2000 Metric Ton/Year Wuhan Fortuna Chemical Co.,Ltd Contact Supplier
High Quality 99% Sulfuric acidcopper(2+) salt (1:1), hydrate (1:5) 7758-99-8 ISO Producer
Cas No: 7758-99-8
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Factory Supply Copper(Ii)Sulfatepentahydrate
Cas No: 7758-99-8
No Data 1 1 Ality Chemical Corporation Contact Supplier

7758-99-8 Usage

Description

Copper(II) sulfate pentahydrate is known as blue vitriol. It is an odorless blue crystal that readily dissolves in water. It is also soluble in methanol, glycerol and slightly soluble in ethanol. The highly toxic, non-combustible has a nauseating metallic taste and turns white when dehydrated. Structurally, in the pentahydrate molecule, each copper(II) ions is surrounded by four water molecules in the corners and the fifth water molecule is attached by hydrogen bonding. Copper (II) sulfate has many applications including preparation of Bordeaux mixture, a fungicide preparation. Electroplating, timber preservation and textile industry use copper (II) sulfate.

Chemical Properties

Copper sulfate is a greenish-white crystalline solid; the pentahydrate is Blue powder or granules, or ultramarine crystalline solid.

Uses

Used as a source of Cu2+ ions

Uses

Anhydr salt for detecting and removing trace amounts of water from alcohols and other organic Compounds; as fungicide. Pentahydrate as agricultural fungicide, algicide, bactericide, herbicide; food and fertilizer additive; in insecticide mixtures; in manufacture of other Cu salts; as mordant in textile dyeing; in preparation of azo dyes; in preserving hides; in tanning leather; in preserving wood; in electroplating solutions; as battery electrolyte; in laundry and metal-marking inks; in petroleum refining; as flotation agent; pigment in paints, varnishes and other materials; in mordant baths for intensifying photographic negatives; in pyrotechnic compositions; in water-resistant adhesives for wood; in metal coloring and tinting baths; in antirusting compositions for radiator and heating systems; as reagent toner in photography and photoengraving; etc.

Uses

Copper (II) sulfate pentahydrate salt may be used for the fabrication of copper nanoparticles by chemical reduction. The pentahydrate salt of copper may be used as a catalyst for the conversion of aromatic aldehydes to primary amides via aldoximes. Reduced graphene oxide-supported copper nanoparticles (rGO/Cu NPs) may be prepared by copper (II) sulfate pentahydrate and graphitic precursors. An aqueous electrolytic bath containing CuSO4.5H2O as one of the constituents was used for the preparation of Cu2ZnSnS4 (CZTS) thin film solar cell. Ferric chloride hexahydrate (FeCl3.6H2O) and copper(II) sulfate pentahydrate (CuSO4.5H2O) may be used to fabricate Fe-Cu binary oxide sorbents for arsenic removal applications.

Definition

ChEBI: Copper(II) sulfate pentahydrate is the pentahydrate of copper(2+) sulfate. A bright blue crystalline solid. It is a hydrate and a metal sulfate. It contains a copper(II) sulfate.

Application

Copper(II) sulfate pentahydrate has been used:as an additive in trace element solution preparation in solid glucose minimal media.as a component of adamsII solution in Pneumococcal media.in the preparation of alginate gel for drug encapsulation.Copper(II) sulfate is an inorganic Lewis acid commonly used to promote acid catalyzed organic reactions. It is used as a reagent for the synthesis of copper carbenoids. It can also act as an effective redox catalyst in combination with other mixed oxidizing systems.Copper Sulfate Pentahydrate Fine Crystals serve as the main ingredient for manufacturing Bordeaux and Burgundy mixtures that are used as algaecides, both on the farm and to ensure safe water supplies. Bordeaux mixtures are also employed to adjust and maintain copper deficient soils to optimum levels.

Definition

A green mineral consisting of copper(II) carbonate and hydroxide (CuCO3.Cu(OH)2). It is used as an ore and a pigment.

Definition

malachite: Apresumptive test for blood. Thereagent is the dye leucomalachitegreen dissolved in water along withsodium perborate (NaBO3). A bluegreencolour indicates a positive result.

General Description

Blue crystalline granules or powder. Melting point 110°C (with decomposition). Non-combustible. Nauseating metallic taste. Odorless. White when dehydrated.

Air & Water Reactions

Slowly effloresces in air. Water soluble.

Reactivity Profile

Copper sulfate pentahydrate can be dehydrated by heating. Serves as a weak oxidizing agent. Causes hydroxylamine to ignite. Gains water readily. The hydrated salt is vigorously reduced by hydroxylamine [Mellor 8:292(1946-1947)]. Both forms are incompatible with finely powdered metals. Both are incompatible with magnesium, corrode steel and iron, may react with alkalis, phosphates, acetylene gas, hydrazine, or nitromethane, and may react with beta-naphthol, propylene glycol, sulphathiazole and triethanolamine if the pH exceeds 7 . Both act as acidic salts, corrode metals and irritate tissues.

Fire Hazard

Literature sources indicate that Copper sulfate pentahydrate is nonflammable.

Potential Exposure

Copper sulfate is used as intermediate and wood preservative; also used in production of copper compounds; to detect and to remove trace amounts of water from alcohols and organic compounds; as a fungicide and algicide; in veterinary medicine and others.

Shipping

UN3288 Toxic solids, inorganic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Aqueous solution is an acid. May form explosive materials on contact with acetylene and nitromethane. Incompatible with strong bases; hydroxylamine, magnesium; zirconium, sodium hypobromite, hydrazine.

Waste Disposal

Copper-containing soluble wastes can be concentrated through the use of ion exchange, reverse osmosis, or evaporators to the point where copper can be electrolytically removed and sent to a reclaiming firm. If recovery is not feasible, the copper can be precipitated through the use of caustics and the sludge deposited in a chemical waste landfill Add soda ash to waste CuSO4 solution; let stand 24 hours. Decant and neutralize solution before flushing to sewer. Landfill sludge.
InChI:InChI=1/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2

7758-99-8 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
Alfa Aesar (14178)  Copper(II) sulfate pentahydrate, ACS, 98.0-102.0%    7758-99-8 500g 518.0CNY Detail
Alfa Aesar (14178)  Copper(II) sulfate pentahydrate, ACS, 98.0-102.0%    7758-99-8 2kg 1226.0CNY Detail
Alfa Aesar (A11262)  Copper(II) sulfate pentahydrate, 99%    7758-99-8 1000g 514.0CNY Detail
Alfa Aesar (A11262)  Copper(II) sulfate pentahydrate, 99%    7758-99-8 5000g 1107.0CNY Detail
Alfa Aesar (A11262)  Copper(II) sulfate pentahydrate, 99%    7758-99-8 25000g 4428.0CNY Detail
Aldrich (469130)  Copper(II)sulfatepentahydrate  99.995% trace metals basis 7758-99-8 469130-50G 989.82CNY Detail
Aldrich (469130)  Copper(II)sulfatepentahydrate  99.995% trace metals basis 7758-99-8 469130-250G 3,418.74CNY Detail
Sigma-Aldrich (209198)  Copper(II)sulfatepentahydrate  ACS reagent, ≥98.0% 7758-99-8 209198-5G 343.98CNY Detail
Sigma-Aldrich (209198)  Copper(II)sulfatepentahydrate  ACS reagent, ≥98.0% 7758-99-8 209198-100G 386.10CNY Detail
Sigma-Aldrich (209198)  Copper(II)sulfatepentahydrate  ACS reagent, ≥98.0% 7758-99-8 209198-250G 635.31CNY Detail
Sigma-Aldrich (209198)  Copper(II)sulfatepentahydrate  ACS reagent, ≥98.0% 7758-99-8 209198-500G 1,054.17CNY Detail
Sigma-Aldrich (209198)  Copper(II)sulfatepentahydrate  ACS reagent, ≥98.0% 7758-99-8 209198-2.5KG 3,149.64CNY Detail

7758-99-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name copper(II) sulfate pentahydrate

1.2 Other means of identification

Product number -
Other names csp

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7758-99-8 SDS

7758-99-8Synthetic route

copper(I) oxide

copper(I) oxide

dimethyl sulfate
77-78-1

dimethyl sulfate

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
at 160℃; for 0.166667h; Inert atmosphere;94%
copper(I) sulfide
22205-45-4

copper(I) sulfide

A

copper(I) oxide

copper(I) oxide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With oxygen In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;A 50%
B n/a
With O2 In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;;A 50%
B n/a
With oxygen byproducts: SO2; over 500°C;
copper (II) carbonate hydroxide

copper (II) carbonate hydroxide

sulfuric acid
7664-93-9

sulfuric acid

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In water
Cu(2+)*2Cu(1+)*2SO3(2-)=Cu(CuSO3)2

Cu(2+)*2Cu(1+)*2SO3(2-)=Cu(CuSO3)2

A

copper(II) sulfate
7758-99-8

copper(II) sulfate

B

copper(II) oxide

copper(II) oxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: SO3(2-); thermal decompn., corundum crucible, 226°C, 260-375°C;
water
7732-18-5

water

copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In water
copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;
In neat (no solvent) rapid oxidation to CuSO4;;
In neat (no solvent) oxidation;;
water
7732-18-5

water

sodium sulfate
7757-82-6

sodium sulfate

A

copper(II) sulfate
7758-99-8

copper(II) sulfate

B

sodium hydroxide
1310-73-2

sodium hydroxide

Conditions
ConditionsYield
In not given Electrolysis; arrangement with diaphragms; Cu anode; liquid film between 2 porous walls of separation between anode and cathode region, regenaration by circulation;;
iron sulfide

iron sulfide

oxygen
80937-33-3

oxygen

copper(II) oxide

copper(II) oxide

A

iron(III) oxide

iron(III) oxide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

iron(III) sulfate

iron(III) sulfate

copper(I) sulfide
22205-45-4

copper(I) sulfide

iron sulfide

iron sulfide

sodium chloride
7647-14-5

sodium chloride

copper(II) oxide

copper(II) oxide

A

iron(III) oxide

iron(III) oxide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

C

copper dichloride

copper dichloride

Conditions
ConditionsYield
With sulfur dioxide; oxygen byproducts: Na2SO4;
With sulfur dioxide; oxygen byproducts: Na2SO4;
copper(I) sulfide
22205-45-4

copper(I) sulfide

iron sulfide

iron sulfide

sodium chloride
7647-14-5

sodium chloride

copper(II) oxide

copper(II) oxide

A

iron(III) oxide

iron(III) oxide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

C

copper dichloride

copper dichloride

Conditions
ConditionsYield
With oxygen byproducts: Na2SO4, SO2;
With oxygen byproducts: Na2SO4, SO2;
copper(I) sulfide
22205-45-4

copper(I) sulfide

sodium chloride
7647-14-5

sodium chloride

A

copper(II) sulfate
7758-99-8

copper(II) sulfate

B

copper(l) chloride

copper(l) chloride

Conditions
ConditionsYield
With oxygen byproducts: Na2SO4; slight prodn. of CuSO4 at the main react. of roasting of Cu2S between 250 and 350°C;
With oxygen byproducts: Na2SO4; slight prodn. of CuSO4 at the main react. of roasting of Cu2S between 250 and 350°C;
copper(I) sulfide
22205-45-4

copper(I) sulfide

sodium chloride
7647-14-5

sodium chloride

A

disulfur dichloride
10025-67-9

disulfur dichloride

B

copper oxychloride

copper oxychloride

C

copper(II) sulfate
7758-99-8

copper(II) sulfate

D

copper dichloride

copper dichloride

Conditions
ConditionsYield
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.;
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.;
copper(I) sulfide
22205-45-4

copper(I) sulfide

sodium chloride
7647-14-5

sodium chloride

A

copper oxychloride

copper oxychloride

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

C

copper dichloride

copper dichloride

Conditions
ConditionsYield
With oxygen between 350 and 375°C at roasting of Cu2S; oxidn. of CuCl, produced at lower temp. in the main react., in presence of NaCl and Na2SO4, latter produced at lower temp.; information about the react. eqs. in detail;
With oxygen between 350 and 375°C at roasting of Cu2S; oxidn. of CuCl, produced at lower temp. in the main react., in presence of NaCl and Na2SO4, latter produced at lower temp.; information about the react. eqs. in detail;
copper(l) chloride

copper(l) chloride

A

copper(I) sulfate

copper(I) sulfate

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sulfuric acid In sulfuric acidA 0%
B n/a
sulfur dioxide
7446-09-5

sulfur dioxide

copper(l) chloride

copper(l) chloride

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With air In water
sulfuric acid
7664-93-9

sulfuric acid

copper(l) chloride

copper(l) chloride

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In sulfuric acid byproducts: HCl, SO2; with concd. H2SO4;;
copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

sulfur dioxide
7446-09-5

sulfur dioxide

copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With air In not given
sulfur trioxide
7446-11-9

sulfur trioxide

copper(II) sulfide

copper(II) sulfide

A

disulfur trioxide

disulfur trioxide

B

sulfur dioxide
7446-09-5

sulfur dioxide

C

sulfur
7704-34-9

sulfur

D

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
360°C in vac.;
iron(III) sulfate

iron(III) sulfate

copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
In not given
sulfuric acid
7664-93-9

sulfuric acid

copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
roasting at 200 - 300°C then product treated with H2SO4;
roasting at 200 - 300°C then product treated with H2SO4;
With air In not given
oxygen
80937-33-3

oxygen

copper(II) sulfide

copper(II) sulfide

copper(II) sulfate
7758-99-8

copper(II) sulfate

copper(II) oxide

copper(II) oxide

A

sulfur dioxide
7446-09-5

sulfur dioxide

B

copper(II) sulfide

copper(II) sulfide

C

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sulfur In neat (no solvent) on heating with excess sulphur;;A n/a
B n/a
C >1
copper(II) oxide

copper(II) oxide

A

copper(II) sulfide

copper(II) sulfide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sulfur In water boiling the colloid soln.;
With water; sulfur In neat (no solvent) triuration with sulphur and H2O, heating in a closed tube up to 100°C;;
With S In water boiling the colloid soln.;
copper(II) oxide

copper(II) oxide

A

copper(I) oxide

copper(I) oxide

B

sulfur dioxide
7446-09-5

sulfur dioxide

C

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sulfur In neat (no solvent) on heating (excess of CuO);;
copper(II) oxide

copper(II) oxide

A

sulfur trioxide
7446-11-9

sulfur trioxide

B

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sulfur dioxide In neat (no solvent) byproducts: Cu2O; heating CuO with SO2;; formation of SO3 and CuSO4;;
With SO2 In neat (no solvent) byproducts: Cu2O; heating CuO with SO2;; formation of SO3 and CuSO4;;
1-acetyl-2-octanoylhydrazine
1007705-71-6

1-acetyl-2-octanoylhydrazine

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu(1-acetyl-2-octanoylhydrazine(-2H))

Cu(1-acetyl-2-octanoylhydrazine(-2H))

Conditions
ConditionsYield
With aq. NH3 In ethanol; water to aq. soln. of metal salt added aq. NH3 (pH 8-11); soln. of ligand in EtOH added (molar ratio metal:ligand = 1:1 or 1:2); after 5 min ppt. filtered; washed (EtOH); dried (air);99.8%
copper(II) sulfate
7758-99-8

copper(II) sulfate

dipyrazine[2,3-f:2’,3’-h]quinoxaline
217-90-3

dipyrazine[2,3-f:2’,3’-h]quinoxaline

C14H8N4*Cu(2+)*O4S(2-)

C14H8N4*Cu(2+)*O4S(2-)

Conditions
ConditionsYield
In ethanol for 0.5h; Reflux;99.5%
pyrite

pyrite

copper(II) sulfate
7758-99-8

copper(II) sulfate

A

copper(I) sulfide
22205-45-4

copper(I) sulfide

B

iron(II) sulfate

iron(II) sulfate

Conditions
ConditionsYield
In water byproducts: H2SO4; pptn. of Cu2S (99.3%) and formation of FeSO4 and H2SO4 by reaction of 5%ic CuSO4- soln. with FeS2 at 200 °C in presence of quartz; quartz prevents formation of Fe2O3, Cu2O and CuS as by-products; formation of CuS with higher per cent FeS2;;A 99.3%
B n/a
In water byproducts: H2SO4; pptn. of Cu2S (99.3%) and formation of FeSO4 and H2SO4 by reaction of 5%ic CuSO4- soln. with FeS2 at 200 °C in presence of quartz; quartz prevents formation of Fe2O3, Cu2O and CuS as by-products; formation of CuS with higher per cent FeS2;;A 99.3%
B n/a
oxovanadium(IV) sulfate

oxovanadium(IV) sulfate

water
7732-18-5

water

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu0.13V2O5.00*1.4H2O

Cu0.13V2O5.00*1.4H2O

Conditions
ConditionsYield
In water Electrochem. Process; 0.075 M VOSO4 and 0.075 M CuSO4 oxidized at 25 °C E=1.0 V(Ag/AgCl);99%
oxovanadium(IV) sulfate

oxovanadium(IV) sulfate

water
7732-18-5

water

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu0.15V2O5.00*1.1H2O

Cu0.15V2O5.00*1.1H2O

Conditions
ConditionsYield
In water Electrochem. Process; 0.075 M VOSO4 and 0.075 M CuSO4 oxidized at 97 °C E=0.5 V(Ag/AgCl);99%
methanesulfonic acid
75-75-2

methanesulfonic acid

treosulfan
1947-62-2

treosulfan

copper(II) sulfate
7758-99-8

copper(II) sulfate

isobutyraldehyde
78-84-2

isobutyraldehyde

2,3-O-isobutylidene-D-threitol 1,4-bis(methanesulfonate)

2,3-O-isobutylidene-D-threitol 1,4-bis(methanesulfonate)

Conditions
ConditionsYield
With potassium carbonate In ethyl acetate; toluene98%
N-phenyl-1H-benzo[d]imidazole-2-carbothioamide
90430-71-0

N-phenyl-1H-benzo[d]imidazole-2-carbothioamide

copper(II) sulfate
7758-99-8

copper(II) sulfate

sulfato(benzimidazole-2-N-phenylcarbothioamide)copper(II)

sulfato(benzimidazole-2-N-phenylcarbothioamide)copper(II)

Conditions
ConditionsYield
With sulfuric acid In methanol; water byproducts: C6H5NH2*H2SO4; soln. of CuSO4 in MeOH-H2O (10:1) added to soln. of org. ligand in MeOH;stirred; concd. H2SO4 added; stirred (1 h, room temp.); kept (24 h); ppt. filtered off; washed with hot and then cold MeOH; dried in desiccator (75°C, 5 h); elem. anal.;98%
3,5-diiodo-l-tyrosine
300-39-0

3,5-diiodo-l-tyrosine

copper(II) sulfate
7758-99-8

copper(II) sulfate

3,5-diiodo L-tyrosine copper complex

3,5-diiodo L-tyrosine copper complex

Conditions
ConditionsYield
Stage #1: 3,5-diiodo-l-tyrosine With sodium hydroxide In water for 1h;
Stage #2: copper(II) sulfate In water at 20 - 40℃; for 2h;
98%
copper(II) sulfate
7758-99-8

copper(II) sulfate

picrolonic acid
132-42-3

picrolonic acid

copper(II) picrolonate*0.5H2O

copper(II) picrolonate*0.5H2O

Conditions
ConditionsYield
In water aq. soln. of copper(II) sulphate added to aq. picrolonic acid at room temp.; ppt. filtered, washed with water, ethanol, ether, dried in vac. till constant weight, elem. anal.;97%
(8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((lanthanum(3+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid

(8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((lanthanum(3+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid

copper(II) sulfate
7758-99-8

copper(II) sulfate

(8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((copper(2+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid

(8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((copper(2+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid

Conditions
ConditionsYield
Stage #1: (8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((lanthanum(3+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid With trifluoroacetic acid In water for 16h;
Stage #2: copper(II) sulfate In water for 0.5h;
97%
Octanoic acid
124-07-2

Octanoic acid

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
Stage #1: Octanoic acid In water at 30℃; for 0.5h;
Stage #2: With sodium hydroxide In water at 55℃; for 0.5h;
Stage #3: copper(II) sulfate for 2h;
96.57%
Cyanoacetohydrazide
140-87-4

Cyanoacetohydrazide

copper(II) sulfate
7758-99-8

copper(II) sulfate

{Cu(C3H4N3O)2(H2O)2}
118613-37-9

{Cu(C3H4N3O)2(H2O)2}

Conditions
ConditionsYield
In ethanol; water refluxing (EtOH/water 1:1, 1 h), pptn.; sepn. (hot filtration), washing (hot EtOH), drying (vac., over CaCl2); elem. anal.;96%
[(CH2)5NCH2C6H2OHC4H9CHNC6H4]2
524679-19-4

[(CH2)5NCH2C6H2OHC4H9CHNC6H4]2

water
7732-18-5

water

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu[(CH2)5NCH2C6H2OHC4H9CHNC6H4]2(2+)*SO4(2-)*4H2O=Cu[(CH2)5NCH2C6H2HOC4H9CHNC6H4]2SO4*4H2O

Cu[(CH2)5NCH2C6H2OHC4H9CHNC6H4]2(2+)*SO4(2-)*4H2O=Cu[(CH2)5NCH2C6H2HOC4H9CHNC6H4]2SO4*4H2O

Conditions
ConditionsYield
In methanol soln. of ligand in MeOH was stirred with soln. of metal salt in MeOH overnight; solvent was removed in vacuo, recrystd. from hexane-diisopropyl ether; elem. anal.;96%
diethyl ether
60-29-7

diethyl ether

copper(II) sulfate
7758-99-8

copper(II) sulfate

{(Z)-1,3-Diphenyl-3-[(Z)-trimethylsilanyl-imino]-propenyl}-trimethylsilanyl-amine
158566-96-2

{(Z)-1,3-Diphenyl-3-[(Z)-trimethylsilanyl-imino]-propenyl}-trimethylsilanyl-amine

[Cu((N(H)C(C6H5))2CH)2]*2C2H5OC2H5

[Cu((N(H)C(C6H5))2CH)2]*2C2H5OC2H5

Conditions
ConditionsYield
In diethyl ether; water (Ar); using Schlenk techniques; addn. of soln. of (H(N(SiMe3)C(Ph))2CH) in Et2O to suspn. of CuSO4 in H2O; stirring at room temp. for 18 h; washing with light petroleum (b.p. 60-80°C); crystn. from Et2O;96%
copper(II) sulfate
7758-99-8

copper(II) sulfate

potassium iodide
7681-11-0

potassium iodide

copper(I) iodide

copper(I) iodide

Conditions
ConditionsYield
In ethanol Kinetics; byproducts: I2, K2SO4; dehydrated solns. of CuSO4 (0.0008 mol/l) and KI (0.0081 mol/l) in EtOH were mixed under protective dried N2 atm.; optimized temp. was 291.15 K,feed flow rate - 2.3 ml/min; suspn. filtered by vac. extract filter; ppt. dried in oven at 353 K for 2-3 h;95.39%
With SiW12O40(4-) In ethanol Irradiation (UV/VIS); SiW12O40(4-) in deaerated EtOH UV-irradiated for 3 h, added to CuSO4 andKI in deaerated EtOH (N2) under stirring; centrifuged, washed (H2O) several times, dried (vac.) at 80°C for5 h;
Conditions
ConditionsYield
With magnesium In water95%
With formic acid In water byproducts: CO2; High Pressure; hydrothermal reaction at 200°C for 18 h; mechanism discussed;;90%
With sulfur dioxide In not given heating; no reaction at ambient temp.;12%
aqueous ammonium acetate

aqueous ammonium acetate

copper(II) sulfate
7758-99-8

copper(II) sulfate

3-amino-4-hydroxytoluene
95-84-1

3-amino-4-hydroxytoluene

4-Bromophenyl isothiocyanate
1985-12-2

4-Bromophenyl isothiocyanate

N-(4-bromophenyl)-N-(5-methyl-1,3-benzoxazol-2-yl)amine
461699-48-9

N-(4-bromophenyl)-N-(5-methyl-1,3-benzoxazol-2-yl)amine

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran; acetonitrile95%
With triethylamine In tetrahydrofuran; acetonitrile95%
nicotinic acid
59-67-6

nicotinic acid

copper(II) sulfate
7758-99-8

copper(II) sulfate

copper(II) nicotinate
16230-63-0, 30827-46-4

copper(II) nicotinate

Conditions
ConditionsYield
With NaOH In water equimolar mixt. of nicotinic acid and NaOH added to aq. soln. of CuSO4, refluxed for 15 min; filtered, elem. anal.;95%
potassium tetrakis(1H-4-methyl-pyrazol-1-yl)borate
178411-32-0

potassium tetrakis(1H-4-methyl-pyrazol-1-yl)borate

copper(II) sulfate
7758-99-8

copper(II) sulfate

copper(II) bis[tetrakis(4-methyl-1H-pyrazol-1-yl)borate]

copper(II) bis[tetrakis(4-methyl-1H-pyrazol-1-yl)borate]

Conditions
ConditionsYield
In water byproducts: K2SO4; elem. anal.;95%
potassium thioacyanate
333-20-0

potassium thioacyanate

fluconazole
86386-73-4

fluconazole

copper(II) sulfate
7758-99-8

copper(II) sulfate

[(α-(2,4-difluorophenyl)-α-(1H-1,2,4-triazol-1-ylmethyl)-1H-1,2,4-triazole-1-ethanol)2 copper(II) (thiocyanate)2]n

[(α-(2,4-difluorophenyl)-α-(1H-1,2,4-triazol-1-ylmethyl)-1H-1,2,4-triazole-1-ethanol)2 copper(II) (thiocyanate)2]n

Conditions
ConditionsYield
In methanol High Pressure; CuSO4, fluconazole, KSCN in stoichiometric ratio 1:1:3 and methanol heated in Teflon-lined autoclaves at 120 °C for 3 days; followed by slow cooling to room temp.; crystals filtered off; elem. anal.;95%
In water High Pressure; CuSO4, fluconazole, KSCN in stoichiometric ratio 1:1:3 and water heated in Teflon-lined autoclaves at 120 °C for 3 days; followed by slowcooling to room temp.; crystals filtered off; elem. anal.;90%
copper(II) sulfate
7758-99-8

copper(II) sulfate

monosodium glutamate
142-47-2

monosodium glutamate

Cu(L-glutamate)
911657-08-4, 69720-87-2

Cu(L-glutamate)

Conditions
ConditionsYield
Stage #1: copper(II) sulfate; monosodium glutamate With sodium hydroxide In water at 5℃; for 18h; Heating / reflux;
Stage #2: With water
94.2%
(1S,9S)-1,9-bis(1-hydroxy-1-methylethyl)semicorrin-5-carbonitrile

(1S,9S)-1,9-bis(1-hydroxy-1-methylethyl)semicorrin-5-carbonitrile

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu((NCH(C(CH3)2OH)(CH2)2C)CCN(NCH(C(CH3)2OH)(CH2)2C))2

Cu((NCH(C(CH3)2OH)(CH2)2C)CCN(NCH(C(CH3)2OH)(CH2)2C))2

Conditions
ConditionsYield
With sodium hydrogencarbonate In dichloromethane; water 23°C;94%
4-amino-3,5-dinitropyrazole potassium salt

4-amino-3,5-dinitropyrazole potassium salt

water
7732-18-5

water

copper(II) sulfate
7758-99-8

copper(II) sulfate

Cu(4-amino-3,5-dinitropyrazole(-1H))2(H2O)2

Cu(4-amino-3,5-dinitropyrazole(-1H))2(H2O)2

Conditions
ConditionsYield
at 80℃; for 2h;93.6%
potassium [14C]cyanide

potassium [14C]cyanide

copper(II) sulfate
7758-99-8

copper(II) sulfate

[14C]cuprous (I) cyanide

[14C]cuprous (I) cyanide

Conditions
ConditionsYield
With potassium cyanide; sodium metabisulfite In water at 70℃; for 0.2h;93.3%
With sodium metabisulfite
N-benzoyl-beta-alanine
3440-28-6

N-benzoyl-beta-alanine

copper(II) sulfate
7758-99-8

copper(II) sulfate

[Cu2(μ(2)-O2CCH2CH2NHCOC6H5)4]
409108-35-6, 60487-57-2

[Cu2(μ(2)-O2CCH2CH2NHCOC6H5)4]

Conditions
ConditionsYield
With NaOH In water org. ligand dissolved in H2O with NaOH; CuSO4 in H2O added; mixt. heatedfor 12 h at 50°C; ppt. filtered; washed (EtOH, Et2O); dried (vac.); elem. anal.;93%
L-Tartaric acid
87-69-4

L-Tartaric acid

copper(II) sulfate
7758-99-8

copper(II) sulfate

Conditions
ConditionsYield
With sodium hydroxide In water to a soln. of (+)-L-tartaric acid in aq. NaOH an aq. soln. of CuSO4 (equimolar to tartaric acid) was added and the mixt. kept at 20°C overnight;; pptd. was collected, washed with acetone and dried in vac.;;93%
1,8-dihydroxy-4,5-dinitro-anthraquinone
81-55-0

1,8-dihydroxy-4,5-dinitro-anthraquinone

copper(II) sulfate
7758-99-8

copper(II) sulfate

C14H4N2O8(2-)*Cu(2+)

C14H4N2O8(2-)*Cu(2+)

Conditions
ConditionsYield
With sodium hydroxide In water at 90℃; for 2h; pH=9;92.6%
potassium hydridotris(1H-4-methyl-pyrazol-1-yl)borate
180310-44-5

potassium hydridotris(1H-4-methyl-pyrazol-1-yl)borate

copper(II) sulfate
7758-99-8

copper(II) sulfate

copper(II) bis[hydridotris(4-methyl-1H-pyrazol-1-yl)borate]

copper(II) bis[hydridotris(4-methyl-1H-pyrazol-1-yl)borate]

Conditions
ConditionsYield
In water byproducts: K2SO4; elem. anal.;92%
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