21728-26-7Relevant academic research and scientific papers
Regioselective 1,2-Diol Rearrangement by Controlling the Loading of BF3·Et2O and Its Application to the Synthesis of Related Nor-Sesquiterene- and Sesquiterene-Type Marine Natural Products
Wang, Jun-Li,Li, Hui-Jing,Wang, Hong-Shuang,Wu, Yan-Chao
supporting information, p. 3811 - 3814 (2017/07/26)
The regiocontrolled rearrangement of 1,2-diols has been achieved by controlling the loading of BF3·Et2O. Its applicability is showcased by the divergent synthesis of austrodoral, austrodoric acid, and 8-epi-11-nordriman-9-one, as well as a formal synthesis of siphonodictyal B and liphagal. A new light is shed on piancol-type rearrangements that will be useful in diversity-oriented synthesis of related natural products.
The Effect of Reduced Osmium Amounts on the Asymmetric Dihydroxylation of 1-Arylcyclohexenes
McIntosh, John M.,Kiser, E. Jay
, p. 1283 - 1284 (2007/10/03)
The amount of osmium required for satisfactory levels of conversion and asymmetric induction in the AD reaction of 1-arylcyclohexenes has been established.
