2176-82-1Relevant academic research and scientific papers
Perfluorozinc aromatics by direct insertion of zinc into C-F or C-CL bonds
Miller, Alexey O.,Krasnov, Vyacheslav I.,Peters, Dietmar,Platonov, Vyacheslav E.,Miethchen, Ralf
, p. 3817 - 3819 (2000)
For the first time perfluoroaromatic organozinc compounds were obtained by direct action of zinc on C-F bonds in the presence of metal salts (SnCl2, CuCl2, ZnBr2). The reactions are accelerated by ultrasound. The scope of
Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O
Krasnov, Vyacheslav I.,Platonov, Vyacheslav E.,Beregovaya, Irina V.,Shchegoleva, Lyudmila N.
, p. 1797 - 1812 (2007/10/03)
Perfluorinated xylenes and perfluoro-para-cymene undergo hydrodefluorination under the action of Zn(Cu)-DMF-H2O. Hydrogen enters mainly at the benzyl position of para-dialkylbenzenes and at the para position to perfluoroalkyl groups of perfluor
