21779-22-6Relevant academic research and scientific papers
SILVER TRIFLATE-PROMOTED COUPLING REACTIONS OF BENZYLIC AND ALLYLIC SULFIDES WITH O-SILYLATED ENOLATES OF KETONES AND ESTERS, A SYNTHESIS OF (+/-)-AR-TURMERONE
Takeda, Kazuyoshi,Torii, Katsumi,Ogura, Haruo
, p. 265 - 266 (2007/10/02)
Reactions of benzylic and allylic sulfides 1 having 5-mercapto-1-phenyl-1H-tetrazolyl group with O-silylated ketone and ester enolates 2 in the presence of silver triflate gave coupling products 3 in good yield. (+/-)-ar-turmerone was synthesized by this
AN EFFECTIVE ACTIVATION OF ALLYL METHYL ETHERS BY A CATALYTIC AMOUNT OF TRITYL PERCHLORATE IN THE ALLYLATION OF SILYL ENOL ETHERS
Mukaiyama, Teruaki,Nagaoka, Hitoshi,Ohshima, Masahiro,Murakami, Masahiro
, p. 1009 - 1012 (2007/10/02)
In the presence of a catalytic amount of trityl perchlorate, secondary and tertiary allyl methyl ethers smoothly react with silyl enol ethers to afford the corresponding γ,δ-unsaturated carbonyl compounds in good yields.By the combination of this reaction
