218129-85-2

Upstream product

• 53178-46-4 1-<2-(1,3-dithianyl)>cyclohex-3-en-1-ol 
• 930-68-7 cyclohexenone 
• 675107-22-9 3-phenylsulfinylmethylcyclohex-2-en-1-one 
• 58775-66-9 3-<(phenylthio)methyl>-2-cyclohexen-1-one 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 67252-14-6 3-hydroxy-1-cyclohexene-1-carbaldehyde 

Downstream Products

• 218129-87-4 3-trityloxymethyl-cyclohex-2-enone 
• 675107-25-2 3-(tert-butyldimethylsiloxymethyl)-2-iodocyclohex-2-en-1-one 
• 675107-24-1 3-(tert-butyldimethylsiloxymethyl)cyclohex-2-en-1-one 
• 620590-41-2 3-hydroxymethyl-2-(1-propenyl)cyclohex-2-en-1-one 
• 675107-23-0 3-(tert-butyl-dimethyl-silanyloxymethyl)-cyclohex-2-enol 
• 218129-86-3 3-trityloxymethyl-cyclohex-2-enol 

Relevant academic research and scientific papers

Different Reaction Modes for the Oxidative Dimerization of Epoxyquinols and Epoxyquinones. Importance of Intermolecular Hydrogen-Bonding

An oxidative dimerization reaction, involving the three successive steps of oxidation, 6π-electrocyclization, and Diels-Alder reaction, has been experimentally and theoretically investigated for the three 2-alkenyl-3-hydroxymethyl-2-cyclohexen-1-one deriv

Studies on the substituted 3-aminopropan-1-ol motif of lycoctonine class norditerpenid alkaloids: A novel route to 3-hydroxymethylcyclohex-2-enone

Pursuing our interest in methyllcaconitine (MLA), we have designed a synthetic route to substituted ring-A of lycoctonine class norditerpenoid alkaloids. A novel synthesis of 3-hydroxymethylcyclohex-2-enone has been achieved starting from cyclohex-2-enone. Key reactions are: 1,2-addition of 1,3-dithiane followed by allylic rearrangement, 1,4-hydrocyanation, Wittig reaction and conversion into the substituted N-ethyl-3-aminopropan-1-ol motif of these neopentyl-like alcohols.