218129-87-4

Basic information

• Product Name: 3-trityloxymethyl-cyclohex-2-enone
• Synonyms: 3-trityloxymethyl-cyclohex-2-enone
• CAS NO: 218129-87-4
• Molecular Weight: 368.475
• Mol File: 218129-87-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-trityloxymethyl-cyclohex-2-enone(CAS DataBase Reference)
• NIST Chemistry Reference: 3-trityloxymethyl-cyclohex-2-enone(218129-87-4)
• EPA Substance Registry System: 3-trityloxymethyl-cyclohex-2-enone(218129-87-4)

Safety Data

• Hazardous Substances Data: 218129-87-4(Hazardous Substances Data)

Upstream product

• 53178-46-4 1-<2-(1,3-dithianyl)>cyclohex-3-en-1-ol 
• 218129-85-2 3-hydroxymethylcyclohex-2-en-1-ol 
• 930-68-7 cyclohexenone 
• 218129-86-3 3-trityloxymethyl-cyclohex-2-enol 

Relevant articles and documents

Studies on the substituted 3-aminopropan-1-ol motif of lycoctonine class norditerpenid alkaloids: A novel route to 3-hydroxymethylcyclohex-2-enone

Pursuing our interest in methyllcaconitine (MLA), we have designed a synthetic route to substituted ring-A of lycoctonine class norditerpenoid alkaloids. A novel synthesis of 3-hydroxymethylcyclohex-2-enone has been achieved starting from cyclohex-2-enone. Key reactions are: 1,2-addition of 1,3-dithiane followed by allylic rearrangement, 1,4-hydrocyanation, Wittig reaction and conversion into the substituted N-ethyl-3-aminopropan-1-ol motif of these neopentyl-like alcohols.