21855-35-6Relevant articles and documents
Preparation of dihomoallylic secondary amines through samarium mediated allylation of oximes
Fan, Xuesen,Zhang, Yongmin
, p. 5475 - 5478 (2002)
The addition of allylsamarium bromide to oximes derived from aromatic aldehydes and methyl aryl ketones was studied and the dihomoallylic secondary amines were obtained in moderate to high yields under mild conditions.
Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes
Zhao, Yu,Hoveyda, Amir H.,Schrock, Richard R.
supporting information; experimental part, p. 784 - 787 (2011/05/05)
The utility of W-alkylidene complexes for enyne ring-closing metathesis is demonstrated in a direct comparison with Mo-based analogs. Tungsten complexes lead to less alkyne oligomerization and higher levels of endo-selectivity and enantioselectivity.
Synthesis of Homoallylamines by the Addition of Allylic Indium Reagents to Azomethines and Nitriles
Jin, Shun-Ji,Araki, Shuki,Butsugan, Yasuo
, p. 1528 - 1532 (2007/10/02)
Triallyldiindium trihalides and allylindate(1-)s reacted with N-benzylideneamines regioselectively at the C-3 carbon on the allyl group to give high yields of homoallylic secondary amines.Primary amines were obtained by the action of an excess of allylic
