2186-33-6

Basic information

• Product Name: N-ALLYL METHACRYLAMIDE
• Synonyms: N-ALLYL METHACRYLAMIDE;2-Propenamide, 2-methyl-N-2-propenyl-;2-Methyl-N-(2-propenyl)-2-propenamide;2-methyl-N-prop-2-enyl-prop-2-enamide;2-methyl-N-prop-2-enylprop-2-enamide;N-allyl-2-methyl-acrylamide
• CAS NO: 2186-33-6
• Molecular Formula: C₇H₁₁NO
• Molecular Weight: 125.17
• EINECS: 218-576-9
• Product Categories: monomer
• Mol File: 2186-33-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 251.5°Cat760mmHg
• Flash Point: 139°C
• Appearance: /
• Density: 0.894g/cm³
• Vapor Pressure: 0.0204mmHg at 25°C
• Refractive Index: 1.446
• CAS DataBase Reference: N-ALLYL METHACRYLAMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N-ALLYL METHACRYLAMIDE(2186-33-6)
• EPA Substance Registry System: N-ALLYL METHACRYLAMIDE(2186-33-6)

Safety Data

• Hazardous Substances Data: 2186-33-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H11NO/c1-4-5-8-7(9)6(2)3/h4H,1-2,5H2,3H3,(H,8,9)

Upstream product

• 79-39-0 Methacrylamide 
• 92954-34-2 O-allyl-N,N'-dicyclohexyl isourea 
• 79-41-4 poly(methacrylic acid) 
• 107-11-9 1-amino-2-propene 
• 920-46-7 Methacryloyl chloride 

Relevant articles and documents

Recent advances in the synthesis of analogues of phytohormones strigolactones with ring-closing metathesis as a key step

In this paper, we synthesized and evaluated the biological activity of structural analogues of natural strigolactones in which the butenolide D-ring has been replaced with a γ-lactam. The key step to obtain the α,β-unsaturated-γ-lactam was an RCM on suitably substituted amides. Strigolactones (SLs) are plant hormones with various developmental functions. As soil signaling chemicals, they are required for establishing beneficial mycorrhizal plant/fungus symbiosis. Beside these auxinic roles, recently SLs have been successfully investigated as antitumoral agents. Peculiar to the SL perception system is the enzymatic activity of the hormone receptor. SARs data have shown that the presence of the butenolide D-ring is crucial to retain the biological activity. The substitution of the butenolide with a lactam might shed light on the mechanism of perception. In the following, a dedicated in silico study suggested the binding modes of the synthesized compounds to the receptor of SLs in plants.

Ruthenium carbene complexes with N,N'-bis(mesityl)imidazol-2-ylidene ligands: RCM catalysts of extended scope

The ruthenium carbene complexes 3a,b bearing imidazol-2-ylidene ligands constitute excellent precatalysts for ring-closing metathesis (RCM) reactions allowing the formation of tri- and tetrasubstituted cycloalkenes. They also apply to annulations that are beyond the scope of the standard Grubbs carbene 1 as well as to ring-closing reactions of acrylic acid derivatives even if the resulting α,β-unsaturated lactones (or lactams) are tri- or tetrasubstituted. The reactivity of 3a was found to be highly dependent on the reaction medium: particularly high reaction rates are observed in toluene, although this solvent also leads to an increased tendency of the catalyst to isomerize the double bonds of the substrates.