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2187-88-4

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2187-88-4 Usage

General Description

1,4,5,8-Naphthalenetetramine, also known as Naphthalenetetramine, is a chemical compound with the molecular formula C10H10N4. It is derived from naphthalene, which is a polycyclic aromatic hydrocarbon often used as an intermediate for other compounds. The tetramine aspect of this compound indicates it contains four amine groups. Like other aromatic amines, it has applications in the production of dyes and polymers. It is not a commonly found compound and its toxicity and environmental effects have not been widely studied.

Check Digit Verification of cas no

The CAS Registry Mumber 2187-88-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,1,8 and 7 respectively; the second part has 2 digits, 8 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 2187-88:
(6*2)+(5*1)+(4*8)+(3*7)+(2*8)+(1*8)=94
94 % 10 = 4
So 2187-88-4 is a valid CAS Registry Number.

2187-88-4Synthetic route

1,4,5,8-tetranitronaphthalene
4793-98-0

1,4,5,8-tetranitronaphthalene

1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

Conditions
ConditionsYield
With tin(ll) chloride In hydrogenchloride; ethanol at 40℃; for 2.5h;82%
Nitroethane
79-24-3

Nitroethane

1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

2,7-dimethylpyrimido[4,5,6-gh]perimidine
2187-86-2

2,7-dimethylpyrimido[4,5,6-gh]perimidine

Conditions
ConditionsYield
With polyphosphoric acid at 110℃; for 3h;78%
1-nitro-1-phenylmethane
622-42-4

1-nitro-1-phenylmethane

1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

2,7-diphenylpyrimido[4,5,6-gh]perimidine
2608-35-7

2,7-diphenylpyrimido[4,5,6-gh]perimidine

Conditions
ConditionsYield
With polyphosphoric acid at 150℃; for 8h;63%
nitromethane
75-52-5

nitromethane

1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

pyrimido[4,5,6-gh]perimidine
194-10-5

pyrimido[4,5,6-gh]perimidine

Conditions
ConditionsYield
With polyphosphoric acid at 100℃; for 14h;56%
1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

naphtho<1,8-cd:5,4-c'd'>bis<1,2,6>thia(SIV)diazine
65989-13-1

naphtho<1,8-cd:5,4-c'd'>bis<1,2,6>thia(SIV)diazine

Conditions
ConditionsYield
With 1-piperidinosulfenyl chloride In diethyl ether at -20℃;25%
1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

dimethyl sulfate
77-78-1

dimethyl sulfate

1,4,5,8-Tetrakis(dimethylamino)naphthalene
134180-29-3

1,4,5,8-Tetrakis(dimethylamino)naphthalene

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran at 25 - 60℃;14%
1,4,5,8-tetra(amino)naphthalene
2187-88-4

1,4,5,8-tetra(amino)naphthalene

tris(dimethylamino)-bromophosphonium bromide

tris(dimethylamino)-bromophosphonium bromide

A

tris(dimethylamino)iminophosphorane hydrobromide
83978-10-3

tris(dimethylamino)iminophosphorane hydrobromide

B

1,6-bis(dimethylamino)-2,5,7,10-tetraazo-1,6λ5-diphosphapyrene
1301606-11-0

1,6-bis(dimethylamino)-2,5,7,10-tetraazo-1,6λ5-diphosphapyrene

Conditions
ConditionsYield
Stage #1: 1,4,5,8-tetra(amino)naphthalene; tris(dimethylamino)-bromophosphonium bromide With triethylamine In chlorobenzene at 20℃; for 72h; Inert atmosphere;
Stage #2: With sodium hexamethyldisilazane In chlorobenzene; toluene for 24h; Inert atmosphere;
A n/a
B 2.14%

2187-88-4Relevant articles and documents

Conjugated perimidine corrosion inhibitor and preparation method thereof

-

Paragraph 0034-0036, (2021/06/02)

The invention discloses a conjugated perimidine corrosion inhibitor and a preparation method thereof. The preparation method comprises the following steps: carrying out acylation and cyclization reaction on 1,4,5,8-tetraminonaphthalene and substituted benzoic acid to obtain dialkyl phenyl perimidine; and 2) performing quaternization reaction on the dialkyl phenyl perimidine and hydrobromic acid to prepare a conjugated perimidine corrosion inhibitor. According to the invention, the conjugated perimidine corrosion inhibitor is high in conjugation degree of molecules, can form a large pi bond to be adsorbed on a metal surface in a planar configuration, is strong in adhesive force, greatly improves the corrosion inhibition rate, can be used as a copper and iron corrosion inhibitor, and has a good corrosion inhibition effect.

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