21876-43-7Relevant academic research and scientific papers
Application of pyridinium ionic liquid as a recyclable catalyst for acid-catalyzed transesterification of jatropha oil
Li, Kai-Xin,Chen, Li,Yan, Zong-Cheng,Wang, Hong-Lin
, p. 151 - 156 (2010)
A series of pyridinium ionic liquids were synthesized and characterized. Acid-catalyzed transesterifications of Jatropha oil were carried out with these ionic liquids under mild reaction conditions. [BSPy]CF3SO3 showed the best catal
Temperature regulated Br?nsted acidic ionic liquid-catalyze esterification of oleic acid for biodiesel application
Rafiee, Ezzat,Mirnezami, Fakhrosadat
, p. 296 - 302 (2017)
By combining phosphotungstic acid (PW) and SO3H- functioned zwitterion, heteropoly anion-based Br?nsted acidic ionic liquids (HPA-ILs) were successfully obtained. Scanning electron microscopy and energy dispersive X-ray spectroscopy were provid
SO3H-functionalized organic-inorganic ionic liquids based on polyoxometalates characterization and their application in C-C coupling reaction
Rafiee, Ezzat,Mirnezami, Fakhrosadat,Kahrizi, Masoud
, p. 332 - 339 (2016)
Different ionic liquids (ILs) with SO3H as functional group were achieved by combining SO3H-functionalized organic cations and polyoxometalates (POM). The obtained salts were characterized and their catalytic activities investigated
Recyclable supported Br?nsted acidic ionic liquid catalysts with non-aromatic cations for the oligomerization of isobutene under mild conditions
Füty?, Júlia,Fehér, Csaba,Hancsók, Jen?,Ispán, Dávid,Juzsakova, Tatjána,Skoda-F?ldes, Rita,Szegedi, ágnes
, (2022/01/13)
Br?nsted acidic ionic liquids with different type of cations (pyridinium, morpholinium, pyrrolidinium, imidazolium), N-sulfoalkyl chain length and different anions (triflate, hydrogensulfate and tetrafluoroborate) were prepared and immobilised on silica by adsorption. The ionic liquids were characterised by NMR and IR. Surface properties and Br?nsted/Lewis acidity of the supported catalysts were also determined. Their catalytic activity and recyclability were compared in the oligomerisation of isobutene to obtain products that can be used as jet fuel blending components after hydrogenation. The results proved that imidazolium ionic liquids can be replaced by less toxic non-aromatic versions without any loss in their activity and stability. By the introduction of shorter sulfoalkyl chain into the cation, excellent results could be obtained even under milder conditions (lower temperature and shorter reaction time). Catalytic activity was shown to correlate to the Br?nsted acidity of the catalyst.
Oligomeric ricinoleic acid preparation promoted by an efficient and recoverable Br?nsted acidic ionic liquid
Gao, Song,He, Liang-Nian,He, Xing,Li, Hong-Ru,You, Fei
supporting information, p. 351 - 361 (2020/03/27)
Raw material from biomass and green preparation processes are the two key features for the development of green products. As a bio-lubricant in metalworking fluids, estolides of ricinoleic acid are considered as the promising substitute to mineral oil wit
Zwitterionic Hydrobromic Acid Carriers for the Synthesis of 2-Bromopropionic Acid from Lactide
Kehrer, Matthias,Mehler, Julian,Taccardi, Nicola,Nagengast, Jens,Kadar, Julian,Collias, Dimitris,Dziezok, Peter,Wasserscheid, Peter,Albert, Jakob
, p. 1063 - 1072 (2018/03/01)
A convenient and highly efficient way of synthesizing 2-bromopropionic acid (2-BrPA) from lactide is presented. The procedure uses ionic liquids obtained from the addition of HBr to ammonium-based zwitterions as the solvent and bromination agent. The buffered HBr acidity, high polarity, and charge stabilizing character of the ionic liquid (IL) enable the synthesis of 2-BrPA with excellent selectivity. The best results are obtained with an imidazolium-based IL, that is, 1-(4-butanesulfonic acid)-3-methylimidazolium bromide ([MIMBS]Br). The HBr loading and water content of the IL are crucial parameters for the bromination reaction. The formed 2-BrPA product can be selectively isolated by extraction from the IL, and the unconverted substrate remains in the [MIMBS]Br IL for the next run. Successful recycling of the IL over four cycles is demonstrated.
Preparation method and application of brphinsted acidic ionic liquid using periodate as anion as well as method for preparing alpha,omega-dialdehyde
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Paragraph 0080; 0083, (2017/05/12)
The invention relates to the field of fine chemical industry, and concretely provides an application of brphinsted acidic ionic liquid using periodate as an anion as well as a preparation method thereof. The invention provides a method for preparing alpha,omega-dialdehyde. The method comprises the following steps: in a condition of a solution, cycloolefin and/or alkylene oxide and an oxidizing agent are contacted, transparent liquid with white deposition is obtained, transparent liquid and white deposition are obtained by separation, wherein the oxidizing agent is brphinsted acidic ionic liquid using periodate as the anion. The brphinsted acidic ionic liquid using periodate as the anion can be used as an oxidizing agent for carrying out an oxidation reaction is provided for the first time, and the method has the advantages of simple and easily operated process, green and environmental protection, cleaning, and repeated recovery and utilization of the oxidizing agent.
A two-phase system for the clean and high yield synthesis of furylmethane derivatives over -SO3H functionalized ionic liquids
Shinde,Rode
, p. 4804 - 4810 (2017/10/19)
A new and effective unique two-phase reaction system is investigated for the high yield production of tri(furyl)methane from furfural and furan. This strategy includes the use of an acidic aqueous phase (water + -SO3H functionalized IL) and furan phase, which significantly suppresses polymer formation, thereby increasing the yield of tri(furyl)methane. Furan serves as a reactant as well as an extraction solvent for the recovery of the condensation products. For comparison, different -SO3H functionalized ionic liquids are prepared and their performances evaluated for the condensation of furan and furfural. The ionic liquids with alkyl chain linkers are found to be more effective and acidic than those with imidazolium linked N-sulfonic acids. In addition, an increase in carbon chain length between imidazole/tri-ethylamine/pyridine and -SO3H, increases the catalytic activity of the respective ionic liquids. Among the several prepared ionic liquids, the strongly acidic imidazolium based butylsulfonic acid 6 shows the best activity with a maximum condensation product yield of 84%. This strategy offers a significantly high yield of the condensation products of furan and furfural compared to the traditional mineral acid route. The activity and stability of the -SO3H functionalized 6 is confirmed from seven successful recycles, in which there is no reduction in its activity. Finally, this new strategy is successfully extended for the condensation of furan derivatives (e.g. furan and 2-methylfuran) with several different aldehydes, ketones and alcohols.
Comprising zwitterionic and/or acid-functionalized ion liquid palladium catalyst system
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Paragraph 0168-0170, (2017/01/26)
The present invention concerns a catalyst system in particular a catalyst system comprising Palladium (Pd), a zwitterion and/or an acid-functionalized ionic liquid, and one or more phosphine ligands, wherein the Pd catalyst can be provided by a complex precursor, such as Pd(CH3COO)2, PdCI2, Pd(CH3COCHCOCH3), Pd (CF3COO)2, Pd(PPh3)4 or Pd2(dibenzylideneacetone)3. Such catalyst systems can be used for e.g. alkoxycarbonylation reactions, carboxylation reactions, and/or in a co-polymerization reaction, e.g. in the production of methyl propionate and/or propanoic acid, optionally in processes forming methyl methacrylate and/or methacrylic acid. Catalyst systems according to the invention are suitable for reactions forming separable product and catalyst phases and supported ionic liquid phase SILP applications.
Green synthesis of dipyrromethanes in aqueous media catalyzed by SO3H-functionalized ionic liquid
Senapak,Saeeng,Jaratjaroonphong,Kasemsuk,Sirion
, p. 1302 - 1310 (2016/02/03)
A mild, efficient and metal-free method was described for the green synthesis of dipyrromethanes from aldehydes and unsubstituted pyrrole catalyzed by SO3H-functionalized ionic liquids (SO3H-ILs) in aqueous media at room temperature. Notably, SO3H-ILs, 1-butylsulfonic-3-methylimidazolium hydrogen sulfate ([bsmim][HSO4]) was the most efficient catalyst for moderate to good yields of the corresponding desired products.
