21877-73-6Relevant academic research and scientific papers
Cu(OAc)2-catalyzed tandem Blaise/Pinner-type reaction for one-pot synthesis of pyrimidin-4-ones
Chun, Yu Sung,Kim, Ju Hyun,Choi, Suh Young,Ko, Young Ok,Lee, Sang-Gi
supporting information, p. 6358 - 6361 (2013/02/23)
A novel tandem Blaise/Pinner-type reaction for the one-pot synthesis of pyrimidin-4-ones is described. The Blaise reaction intermediate, formed by addition of a Reformatsky reagent to a nitrile, reacted with a second nitrile chemoselectively in the presen
Reaction of Benzocinnolinium-5-(N-acyl- and N-benzimido-imides) with Diphenylcyclopropenone
Barr, John J.,Storr, Richard C.,Tandon, Vishnu K.
, p. 1147 - 1149 (2007/10/02)
Benzocinnolinium-5-(N-acylimides) (6; R = Ph, OEt, or Me) give benzocinnoline and 2-substituted-4,5-diphenyloxazin-6-ones (7) on reaction with diphenylcyclopropenone.In contrast, the related benzocinnolinium-5-(N-benzimidoimides) (11; R = H, Ph, or p-tolyl) give stable adduct (12), which on pyrolysis yield benzocinnoline and 1-substituted-2,5,6-triphenylpyrimidin-4-ones.
