21914-90-9

Upstream product

• 77154-90-6 1L-2,3,4,5,6,7-Hexa-O-acetyl-1-desoxy-1-C-hydroxymethyl-myo-inosit 
• 81712-92-7 2L-(2,3,5/4,6)-2,3:4,5-Di-O-isopropyliden-6-O-methyl-1-C-methylen-2,3,4,5,6-pentahydroxycyclohexan 
• 630110-49-5 (1R,2R,3S,4R,5R,6S)-1,2,4-triacetoxy-6-benzyloxymethyl-3,5-dibenzyloxy-6-nitrocyclohexane 
• 630110-47-3 3,5,7-tri-O-benzyl-6-desoxy-1,2-O-isopropylidene-6-nitro-D,L-glycero-α-D-glucoheptafuranose 
• 630110-46-2 3-O-benzyl-6-desoxy-1,2-O-isopropylidene-6-nitro-D,L-glycero-α-D-glucoheptafuranose 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 630110-52-0 1D-3-benzyloxymethyl-2,6-di-O-benzyl-myo-inositol 
• 86845-47-8 1L-1-Desoxy-1-C-hydroxymethyl-2,3:4,5-di-O-isopropyliden-6-O-methyl-myo-inosit 
• 630110-48-4 (1R,2S,3R,4R,5R,6R)-6-benzyloxymethyl-3,5-dibenzyloxy-1,2,4-trihydroxy-6-nitrocyclohexane 

Downstream Products

• 77154-90-6 1L-2,3,4,5,6,7-Hexa-O-acetyl-1-desoxy-1-C-hydroxymethyl-myo-inosit 

Relevant academic research and scientific papers

Transformation of D-Glucose into 1D-3-Deoxy-3-hydroxymethyl-myo-inositol by Stereocontrolled Intramolecular Henry Reaction

(Equation presented) An intramolecular Henry cyclization provides a promising new strategy for the transformation of nitroheptofuranoses into deoxyhydroxy-methylinositols. This method has allowed a stereospecific transformation of D-glucose into 1D-3-deox

Cyclitol Reactions, IX. - Synthesis of 1L-1-Deoxy-1-C-hydroxymethyl-myo-inositol and 1L-1-Deoxy-1-C-hydroxymethyl-chiro-inositol

Hydroboration of the exo-methylene compound 3 with disiamylborane leads to the alcohols 4 and 6.Removal of the protective groups results in the enantiomerically pure, branched-chain (hydroxymethyl)inositols having 1L-myo configuration and 1L-chiro configu