77154-90-6

Upstream product

• 126661-83-4 (1R^*,6S^*)-cyclophellitol 
• 77144-65-1 DL-O-triacetyl-(1,3/2,4)-4-<(benzoyloxy)methyl>-5-cyclohexene-1,2,3-triol 
• 70838-35-6 DL-(1,3/2,4,6)-1,2,3-tri-O-acetyl-4-bromo-6-bromomethyl-1,2,3-cyclohexanetriol 
• 77144-67-3 DL-(1,3/2,4)-4-(hydroxymethyl)-5-cyclohexene-1,2,3-triol 
• 108-24-7 acetic anhydride 
• 77144-68-4 DL-Tetra-O-acetyl-1,2-anhydro-(1,2,3,5/4,6)-6-(hydroxymethyl)-1,2,3,4,5-cyclohexanepentol 
• 86853-32-9 1L-1-Desoxy-1-C-hydroxymethyl-chiro-inosit 
• 21914-90-9 1L-1-Desoxy-1-C-(hydroxymethyl)-myo-inosit 

Downstream Products

• 86853-32-9 1L-1-Desoxy-1-C-hydroxymethyl-chiro-inosit 
• 21914-90-9 1L-1-Desoxy-1-C-(hydroxymethyl)-myo-inosit 

Relevant academic research and scientific papers

Cyclitol Reactions, IX. - Synthesis of 1L-1-Deoxy-1-C-hydroxymethyl-myo-inositol and 1L-1-Deoxy-1-C-hydroxymethyl-chiro-inositol

Hydroboration of the exo-methylene compound 3 with disiamylborane leads to the alcohols 4 and 6.Removal of the protective groups results in the enantiomerically pure, branched-chain (hydroxymethyl)inositols having 1L-myo configuration and 1L-chiro configu

SYNTHESIS OF HEXA-N,O-ACETYL-DL-HYDROXYVALIDAMINE

DL-(1,3,4/2,5,6)-4-amino-6-hydroxymethyl-1,2,3,5-cyclohexanetetrol (DL-hydroxyvalidamine) was first synthesized as the peracetate, which confirmed the proposed structure of the branched-chain aminocyclitol derived by hydrogenolysis of antibiotic validamyc