219697-93-5

Basic information

• Product Name: (2S,3S,4R)-2-benzylamino-1,3,4-dihydroxyoctadecane
• Synonyms: (2S,3S,4R)-2-benzylamino-1,3,4-dihydroxyoctadecane
• CAS NO: 219697-93-5
• Molecular Weight: 497.762
• Mol File: 219697-93-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3S,4R)-2-benzylamino-1,3,4-dihydroxyoctadecane(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S,4R)-2-benzylamino-1,3,4-dihydroxyoctadecane(219697-93-5)
• EPA Substance Registry System: (2S,3S,4R)-2-benzylamino-1,3,4-dihydroxyoctadecane(219697-93-5)

Safety Data

• Hazardous Substances Data: 219697-93-5(Hazardous Substances Data)

Upstream product

• 219697-73-1 (4S,5R)-3-benzyl-4-(hydroxymethyl)-5-vinyl-2-oxazolidinone 
• 943060-96-6 (4S,5S)-3-benzyl-4-(benzyloxymethyl)-5-formyl-2-oxazolidinone 
• 219697-74-2 (4S,5R)-3-benzyl-4-(benzyloxymethyl)-5-vinyl-2-oxazolidinone 
• 100-39-0 benzyl bromide 
• 219697-89-9 (4S,5S)-3-benzyl-4-(benzyloxymethyl)-5-<(1R)-1-(hydroxytetradecyl)>-2-oxazolidinone 

Downstream Products

• 554-62-1 D-ribo-phytosphingosine 

Relevant articles and documents

Highly diastereoselective synthesis of 1,2-amino alcohols via nucleophilic addition of organocerium reagents to 4- and 5- oxazolidinonecarbaldehydes

The reaction of chiral, non-racemic 4- and 5- oxazolidinonecarbaldehydes, 6 and 13, with organocerium reagents proceeds efficiently with good to excellent diastereoselectivity to give syn and anti alcohols, respectively. A model to explain the observed diastereoselectivity of the reaction of 6 and 13 is provided. The utility of this method for the synthesis of amino alcohols is exemplified by the synthesis of C-18-D-ribo- phytosphingosine from the anti alcohol 14f.