219794-83-9Relevant academic research and scientific papers
Complete rearrangement of a multi-porphyrinic rotaxane by metallation-demetallation of the central coordination site
Linke, Myriam,Chambron, Jean-Claude,Heitz, Valerie,Sauvage, Jean-Pierre,Semetey, Vincent
, p. 2469 - 2470 (1998)
A new multiporphyrinic [2]rotaxane has been made in which a gold(III) porphyrin is part of the ring; rotation of the string-like fragment within the ring between two diametrically opposed positions is triggered by metallation-demetallation of the central
Multiporphyrinic rotaxanes: Control of intramolecular electron transfer rate by steering the mutual arrangement of the chromophores
Linke,Chambron,Heitz,Sauvage,Encinas,Barigelletti,Flamigni
, p. 11834 - 11844 (2007/10/03)
A [2]-rotaxane Zn2-Au+ made from a dumbbell component ended by Zn(II) porphyrin stoppers and a ring component incorporating a Au(III) porphyrin has been assembled in 13% yield using the transition metal templating route. 1
