219983-80-9

Basic information

• Product Name: (E)-2-iodoethenyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether
• Synonyms: (E)-2-iodoethenyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether
• CAS NO: 219983-80-9
• Molecular Weight: 308.203
• Mol File: 219983-80-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-2-iodoethenyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-iodoethenyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether(219983-80-9)
• EPA Substance Registry System: (E)-2-iodoethenyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether(219983-80-9)

Safety Data

• Hazardous Substances Data: 219983-80-9(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 108167-50-6 ethynyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether 

Downstream Products

• 250267-05-1 5-ethyl 3-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2E,4E-pentadienoate 
• 250267-07-3 1-[5-methoxy-1E,3E-pentadiene], [2-isopropyl-5-methylcyclohexyl-(1R,2S,5R)]ether 
• 250267-06-2 5-[2-isopropyl-5-methylcyclohexyloxy-(1R,2S,5R)]-2E,4E-pentadienol 
• 250267-04-0 1E,3-butadiene, [2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]ether 
• 250267-02-8 3-[2-isopropyl-5-methylcyclohexyloxy(1R,2S,5R)]-2E-propenal 
• 219983-95-6 1E,3Z-octadiene, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether 
• 197970-24-4 (E,E)-1-l-menthyloxy-1,3-octadiene 
• 219983-90-1 1E-octen-3-ynyl, [2-isopropyl-5-methylcyclohexyl(1R,2S,5R)]ether 

Relevant articles and documents

Photooxygenation of chiral dienol ethers: Asymmetric synthesis of alkoxydioxines

The addition of 1O2 to chiral dienol ethers provides a new route to alkoxydioxines (alkoxyendoperoxides). Depending upon substitution and geometry, the [4+2] cycloaddition is accompanied or even supplanted by [2+2] cycloaddition leading to alkene cleavage and/or ene-like reaction leading to allylic hydroperoxides. The diastereoselectivity of cycloaddition is ultimately limited by the conformational freedom of the dienol ether substrates.