220049-46-7

Upstream product

• 108885-08-1 (1S)-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester 
• 108-95-2 phenol 
• 21286-54-4 Camphorsulfonyl chloride 

Downstream Products

• 220049-53-6 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((1R,2R)-2-phenyl-cyclopropyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-52-5 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((1R,2R)-2-propyl-cyclopropyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-51-4 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((1R,2R)-2-methyl-cyclopropyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-50-3 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((E)-styryl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-49-0 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((E)-pent-1-enyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-48-9 [(1S,2S,4R,6R,7S)-10,10-Dimethyl-4-((E)-propenyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-1-yl]-methanesulfonic acid phenyl ester 
• 220049-47-8 ((1S,2S,3R,4S)-2,3-Dihydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-yl)-methanesulfonic acid phenyl ester 

Relevant academic research and scientific papers

Diastereoselective cyclopropanation of α,β-unsaturated acetals of a novel camphor-derived chiral auxiliary

Reaction of selected α,β-unsaturated aldehydes with phenyl 2,3-dihydroxybornane-10-sulfonate affords acetals which undergo diastereoselective (> 99% de) Simmons-Smith cyclopropanation.