220090-92-6Relevant articles and documents
{4,4-Dimethyl-6,6-bis(1-morpholiniomethyl)-2,2′-[1,2 - ethanediylbis(nitrilomethylidene-N)]diphenolato-O,O′}-copper(II) diperchlorate monohydrate
Shanmuga Sundara Raj,Thirumurugan,Shanmugam,Fun, Hoong-Kun,Manonmani,Kandaswamy
, p. 894 - 896 (1999)
The crystal structure of the title compound, [Cu(C28H38-N4O4)](ClO 4)2·H2O, shows that the CuII ion is in a distorted square-pyramidal environment. The average Cu - O and Cu - N bond lengths are 1.916 (2) and 1.936 (3) A, respectively. Both of the morpholino rings adopt a chair conformation. Even though enough chelating centres are available to coordinate more than one metal atom, because of the steric interaction of the morpholino rings only one Cu atom is coordinated to the ligand.
New salicylaldoximato-borate ligands resulting from anion hydrolysis and their respective copper and iron complexes
Woodhouse, Sidney S.,De Silva, D. Nirosha T.,Jameson, Geoffrey B.,Cutler, Daniel J.,Sanz, Sergio,Brechin, Euan K.,Davies, Casey G.,Jameson, Guy N. L.,Plieger, Paul G.
, p. 11872 - 11881 (2019)
Anion hydrolysis reactions between salicylaldoximato ligands (L′-L′′′) and copper and iron BF4- metal salts, have resulted in the formation of new salicylaldoximato borate containing transition metal complexes: [Fe2(L′ + 2
