22013-86-1

Basic information

• Product Name: Benzene, 1-(2-bromo-2-nitroethenyl)-4-methoxy-
• CAS NO: 22013-86-1
• Molecular Formula: C9H8BrNO3
• Molecular Weight: 258.071
• Mol File: 22013-86-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2-bromo-2-nitroethenyl)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2-bromo-2-nitroethenyl)-4-methoxy-(22013-86-1)
• EPA Substance Registry System: Benzene, 1-(2-bromo-2-nitroethenyl)-4-methoxy-(22013-86-1)

Safety Data

• Hazardous Substances Data: 22013-86-1(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 3179-10-0 1-methoxy-4-(2-nitro-vinyl)-benzene 
• 563-70-2 bromonitromethane 
• 3910-55-2 N-(p-methoxybenzylidene)butylamine 
• 64-17-5 ethanol 
• 22013-85-0 4-(1,2-dibromo-2-nitro-ethyl)-anisole 
• 127-08-2 potassium acetate 

Downstream Products

• 43055-39-6 [Cyano-(4-methoxy-phenyl)-methyl]-triphenyl-phosphonium; bromide 
• 3179-10-0 1-methoxy-4-(2-nitro-vinyl)-benzene 
• 1222137-22-5 3-bromo-4-(4-methoxyphenyl)-6,6-dimethyl-5,6-dihydro-4H-1,2-oxazine N-oxide 
• 1258432-56-2 (2R,3R)-3-(4-methoxyphenyl)-6,6-dimethyl-2-nitro-2,3,6,7-tetrahydrobenzofuran-4(5H)-one 
• 1258432-58-4 (4R,5R)-methyl-4-(4-methoxyphenyl)-2-methyl-5-nitro-4,5-dihydrofuran-3-carboxylate 
• 1258432-60-8 1-((4R,5R)-4-(4-methoxyphenyl)-2-methyl-5-nitro-4,5-dihydrofuran-3-yl)ethanone 
• 132784-90-8 3-(4-methoxyphenyl)-6,6-dimethyl-2-nitro-2,3,6,7-tetrahydrobenzofuran-4(5H)-one 

Relevant articles and documents

Organocatalytic Asymmetric Synthesis of Aza-Spirooxindoles via Michael/Friedel-Crafts Cascade Reaction of 1,3-Nitroenynes and 3-Pyrrolyloxindoles

An asymmetric [3+3] cyclization of nitroenynes and 3-pyrrolyloxindoles has been realized with a chiral bifunctional squaramide catalyst. This Michael/Friedel-Crafts cascade strategy provides a facile and efficient access to enantioenriched polycyclic aza-spirooxindoles with 32-95% isolated yields and excellent stereocontrol under mild reaction conditions.

A novel tandem sequence to pyrrole syntheses by 5-endo-dig cyclization of 1,3-enynes with amines

The synthesis of pentasubstituted pyrroles has been described using molecular iodine from 1,3-enynes and amines via a sequential tandem aza-Michael addition, iodocyclization, and oxidative aromatization. The protocol is simple and efficient to afford the target products at ambient conditions.

SYNTHESIS OF 2-HALOGENO-2-NITROETHENYLARENES

A series of 2-halogeno-2-nitroethenylarenes were obtained as a result of the condensation of halogenonitromethanes with aromatic (heterocyclic) aldehydes in the presence of catalytic amounts of ethylenediamine and also by the addition of halogenonitromethanes to butylarylimines in acetic anhydride.