22024-03-9Relevant academic research and scientific papers
A new mechanism for reactions of carbenes and bicyclo[1.1.0]butanes
Xu,Miebach,Brinker,Smith
, p. 4461 - 4464 (2007/10/02)
Reactions of tricyclo[4.1.0.02,7]heptane (1) with dihalocarbenes and bromine are reported. A new side bond opening mechanism for reactions of carbenes and bicyclo[1.1.0]butanes is proposed.
REACTIONS OF CARBENES WITH COMPOUNDS OF THE BICYCLOBUTANE SERIES. II. REACTION OF DICHLOROCARBENE WITH TRICYCLO2,7>HEPTANES
Koptelov, Yu. B.,Kostikov, R. R.,Molchanov, A. P.
, p. 2181 - 2185 (2007/10/02)
Dichlorocarbene generated under the conditions of phase-transfer catalysis reacts with unsubstituted 1-methyl- and 1-phenyltricyclo2,7>heptanes with the formation of 2-substituted 3-(2,2-dichlorovinyl)-1-cyclohexenes and 1-substituted 7
