220337-41-7Relevant academic research and scientific papers
Preparation and reactions of 3,4-bisstannyl-2(5H)furanones
Carter, Neil B,Mabon, Ross,Richec?ur, Alexandre M.E,Sweeney
, p. 9117 - 9129 (2002)
Bistributylstannyl-2(5H)-furanone 4a has been prepared from 3-(tetrahydropyran-2-yl)oxy but-2-ynoate and shown to exhibit good selectivity in its Stille reactions with a range of halogenated compounds, leading to 4-substituted-3-stannyl-2(5H)-furanones, in generally moderate yield. Under certain reaction conditions, doubly substituted products were also isolated from the reactions. The 3,4-bistrimethylstannyl furanone, 4b, corresponding to 4a was prepared, but decomposed during all attempts to execute Stille reactions upon it.
