220358-42-9

Basic information

• Product Name: (3S,4S)-N-(o-bromobenzyl)pyrrolidine-3,4-diol
• Synonyms: (3S,4S)-N-(o-bromobenzyl)pyrrolidine-3,4-diol
• CAS NO: 220358-42-9
• Molecular Weight: 272.142
• Mol File: 220358-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4S)-N-(o-bromobenzyl)pyrrolidine-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-N-(o-bromobenzyl)pyrrolidine-3,4-diol(220358-42-9)
• EPA Substance Registry System: (3S,4S)-N-(o-bromobenzyl)pyrrolidine-3,4-diol(220358-42-9)

Safety Data

• Hazardous Substances Data: 220358-42-9(Hazardous Substances Data)

Upstream product

• 3959-05-5 2-bromobenzylamine 

Downstream Products

• 220358-44-1 (3S,4S)-N-(o-bromobenzyl)-3,4-bis<(E)-methoxycarbonylethenoyloxy>pyrrolidine 
• 220358-48-5 (3S,4S)-N-(o-bromobenzyl)-3,4-diacetoxypyrrolidine 
• 220358-50-9 (3S,4S)-3,4-diallyloxy-N-(o-bromobenzyl)pyrrolidine 
• 220358-46-3 (3S,4S)-N-(o-bromobenzyl)-3,4-diacryloyloxypyrrolidine 
• 86734-19-2 N-(1-hydroxy-1-benzyl)pyrrole 
• 2051-97-0 1-benzyl-1H-pyrrole 

Relevant articles and documents

Intramolecular 1,5-hydrogen atom transfer radical reaction of pyrrolidine derivatives

Intramolecular 1,5-hydrogen atom transfer radical cyclization reaction of pyrrolidine derivatives was examined. Radical reaction of 3,4-bis(α,β- unsaturated acyloxy)-(8, 9) and 3,4-diacetoxy (13)-N-[(o- halobenzyl)pyrrolidines underwent elimination of two acyloxy groups to give mainly N-benzylpyrrole (11). On the other hand, the similar reaction of 3,4- diallyloxy-N-(o-bromobenzyl)pyrrolidine (16) gave desired hexahydrofuro[3,2- b]pyrroles (17, 18) together with a dimeric hexahydrofuro[3,2-b]pyrrole (19).