22040-02-4

Basic information

• Product Name: Benzene, 1,3-dimethyl-2-phenoxy-
• CAS NO: 22040-02-4
• Molecular Formula: C14H14O
• Molecular Weight: 198.265
• Mol File: 22040-02-4.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzene, 1,3-dimethyl-2-phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,3-dimethyl-2-phenoxy-(22040-02-4)
• EPA Substance Registry System: Benzene, 1,3-dimethyl-2-phenoxy-(22040-02-4)

Safety Data

• Hazardous Substances Data: 22040-02-4(Hazardous Substances Data)

Upstream product

• 576-26-1 2.6-dimethylphenol 
• 603-33-8 triphenylbismuthane 
• 123084-61-7 (2,6-dimethylphenyl)-λ³-iodanediyl diacetate 
• 591-50-4 iodobenzene 
• 608-28-6 2,6-dimethyliodobenzene 
• 576-22-7 2-Bromo-m-xylene 
• 108-95-2 phenol 
• 108-86-1 bromobenzene 
• 16081-16-6 sodium 2,6-dimethylphenolate 
• 79169-56-5 tetraphenylbismuthonium trifluoroacetate 
• 83566-43-2 tetraphenyl-bismuth trifluoroacetate 
• 28899-97-0 triphenylbismuth(V) diacetate 

Downstream Products

• 576-26-1 2.6-dimethylphenol 

Relevant articles and documents

Spontaneous generation of chirality in simple diaryl ethers

We studied the spontaneous formation of chiral crystals of four diaryl ethers, 3-phenoxybenzaldehyde, 1; 1,3-dimethyl-2-phenoxybenzene, 2; di(4-aminophenyl) ether, 3; and di(p-tolyl) ether, 4. Compounds 1, 3, and 4 form conformationally chiral molecules i

Magnetically recyclable nano copper/chitosan in O-arylation of phenols with aryl halides

Interaction of chitosan (CS) with Fe3O4, followed by embedding Cu nanoparticles (NPs) on the magnetic surface through adsorption of Cu2+, and its reduction to Cuo via NaBH4, offers a reusable efficient catalyst (Fe3O4/CS-Cu NPs) that is employed in cross-coupling reactions of aryl halides with phenols, which affords the corresponding diaryl ethers, with good to excellent yields. The catalyst is completely recoverable from the reaction mixture by using an external magnet. It can be reused four times, without significant loss in its catalytic activity.

Synthesis of highly functionalized diaryl ethers by copper-mediated O-arylation of phenols using trivalent arylbismuth reagents

Highly functionalized diaryl ethers were prepared by copper(II) acetate mediated O-arylation reaction of phenols using trivalent organobismuthanes. The reaction is performed under simple conditions and tolerates a wide diversity of functional groups on the phenol and on the organobismuth reagent. Substoichiometric amounts of catalyst can be used by performing the reaction under an oxygen atmosphere. The N-arylation of pyridones is also reported. Highly functionalized diaryl ethers were prepared by a copper(II) acetate mediated O-arylation reaction of phenols using trivalent organobismuthanes (see scheme). The reaction is performed under simple conditions and tolerates a wide diversity of functional groups on the phenol and on the organobismuth reagent. Substoichiometric amounts of catalyst can be used by performing the reaction under an oxygen atmosphere. The N-arylation of pyridones is also reported. FG=functional group.