220422-63-9Relevant academic research and scientific papers
Studies on some reactions of cyclopalladated azobenzenes with N,O-chelators
Bag,Misra,Sinha
, p. 4109 - 4114 (1998)
The synthesis and characterization of new planar mixed chelates of the type [Pd(A)(N,O)] (A=ortho-metallated azobenzene or its substituted derivatives, A1 to A5, N,O=2-picolinato (pic), quinaldato (qnd), 8-quinolinolato (q) and 2-methyl-5-sulphonic-8-quinolinolato (msq)) are achieved by splitting the halogeno-bridge in [Pd2(A)2Cl2] by aqueous AgNO3 solution followed by the addition of N,O-chelator. [Pd(A2)(N,O)] occurs as isomer [Pd(A3)(N,O)] and the composition have been established using 1H NMR data. The complex composition is supported by elemental analyses and IR data. Cyclic voltammetric studies suggest two successive redox responses correspond to azo reduction.
