22043-65-8

Basic information

• Product Name: 3-Aminocarborane
• Synonyms: 3-Aminocarborane
• CAS NO: 22043-65-8
• Molecular Formula: C₂H₁₃B₁₀N
• Molecular Weight: 159.242
• Mol File: 22043-65-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Aminocarborane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Aminocarborane(22043-65-8)
• EPA Substance Registry System: 3-Aminocarborane(22043-65-8)

Safety Data

• Hazardous Substances Data: 22043-65-8(Hazardous Substances Data)

Upstream product

• 16872-09-6 1,2-dicarba-closo-dodecaborane⁽¹²⁾ 
• 7664-41-7 ammonia 
• 19513-12-3 9-Cl-o-HCB₁₀H₉CH 
• 17819-85-1 9-chloro-m-carborane 
• 17157-02-7 9-iodo-m-carborane 
• 17830-03-4 9-iodo-o-carborane 

Downstream Products

• 32506-49-3 3-(NHSO₂-4-C₆H₄CH₃)-1.2-C₂B₁₀H₁₁ 
• 22043-75-0 3-(N-benzoylamino)-1,2-dicarba-closo-dodecaborane 
• 22464-44-4 3-(NHCONHC₆H₅)-1.2-C₂B₁₀H₁₁ 
• 52374-60-4 3-(NHC₆H₅)-1.2-C₂B₁₀H₁₁ 
• 52374-59-1 3-(NH-4-C₆H₄CH₃)-1.2-C₂B₁₀H₁₁ 

Relevant articles and documents

Ir-Catalyzed Selective B(3)-H Amination of o-Carboranes with NH3

Ammonia gas, NH3, is a cheap and widely used industrial feedstock, which has received tremendous research interests in its functionalization. This work reports a breakthrough in catalytic selective cage B(3)-H amination of o-carboranes with NH3 via Ir-catalyzed B-H/N-H dehydrocoupling, offering convenient and efficient access to a series of 3-NH2-o-carborane derivatives in moderate to high isolated yields with a broad substrate scope. The employment of readily available NH3 gas as the aminating reagent with H2 as the sole byproduct endows the protocol economy, practicability, and environmental friendliness. A plausible reaction mechanism is proposed on the basis of control experiments.