220458-74-2

Upstream product

• 99322-64-2 phenyl (2,3:5,6-di-O-isopropylidene-α-D-mannofuranosyl) sulfone 
• 67222-87-1 phenyl 2,3;5,6-di-O-isopropylidene-1-thio-β-D-mannofuranoside 
• 91510-85-9 phenyl 2,3;5,6-di-O-isopropylidene-1-thio-α-D-mannofuranoside 
• 220458-81-1 (3aS,4R,6R,6aS)-4-Benzenesulfonyl-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[3,4-d][1,3]dioxole 

Downstream Products

• 220458-84-4 Toluene-4-sulfonic acid (3S,4R)-4-(benzyl-tert-butoxycarbonyl-amino)-5-benzyloxy-3-hydroxy-pentyl ester 
• 220458-79-7 (3S,4R)-5-benzyloxy-4--1,3-pentanediol 
• 220458-82-2 phenyl 2-amino-N-benzyl-2N,3O-carbamoyl-2,5-dideoxy-5-iodo-α-D-lyxofuranosyl sulfone 
• 220458-76-4 phenyl 2-amino-N-benzyl-2N,3O-carbamoyl-2-deoxy-α-D-lyxofuranosyl sulfone 
• 220458-78-6 (4R,5S)-3-benzyl-4-benzyloxymethyl-5-(2-hydroxyethyl)-2-oxazolidinone 
• 220458-77-5 (4R,5S)-3-benzyl-4-benzyloxymethyl-5-vinyl-2-oxazolidinone 
• 220458-80-0 (2R,3S)-1-benzyl-2-benzyloxymethyl-3-hydroxypyrrolidine 
• 219697-75-3 (4R,5S)-3-benzyl-4-(hydroxymethyl)-5-vinyl-2-oxazolidinone 
• 220458-72-0 (4S,5S)-3-benzyl-4-formyl-5-vinyl-2-oxazolidinone 
• 98900-30-2 (2R,3S)-2-hydroxymethyl-3-hydroxypyrrolidinium hydrochloride 
• 220458-75-3 phenyl 2-amino-N-benzyl-2N,3O-carbamoyl-2-deoxy-5,6-O-isopropylidene-α-D-lyxofuranosyl sulfone 

Relevant academic research and scientific papers

The preparation of 1-tributylstannyl glycals from 1-phenylsulfonyl glycals via Ni(0)-catalysed coupling with tributylstannylmagnesium bromide

1-Phenylsulfonyl glycals undergo an easy Ni(0)-catalysed coupling with tributylstannylmagnesium bromide to give the corresponding 1-tributylstannyl glycals in good yield.

Synthesis of (2R,3S)-3-hydroxy-2-hydroxymethylpyrrolidine from (4S,5S)-3-benzyl-4-formyl-5-vinyl-2-oxazolidinone

(4S,5S)-3-BenzyI-4-formyl-5-vinyl-2-oxazolidinone (2), readily prepared via the reductive elimination of the mannose-derived iodo phenyl sulfone (6b), is used in the synthesis of the alkaloid (2R,3S)-3-hydroxy-2-hydroxymethylpyrrolidine (1).