99322-64-2

Upstream product

• 67222-87-1 phenyl 2,3;5,6-di-O-isopropylidene-1-thio-β-D-mannofuranoside 

Downstream Products

• 220458-74-2 (2S,3R)-5-Benzenesulfonyl-2-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,3-dihydro-furan-3-ol 

Relevant academic research and scientific papers

113. Deoxy-nitrosugars. 11th Communication. Reaction of 1-C-Nitroglycosyl Halides and 1-C-Nitroglycosyl Sulfones with Dialkyl-Phosphite Anions: Nucleophilic Attack vs. Single-Electron Transfer

Treatment of the chloro-nitro-ribofuranose 7 with KPO(OMe)2 gave the O-amino phosphate 8 (5percent) and the nitrile 9 (62percent).Compound 9 was also obtained by the reaction of 8 with KPO(OMe)2, and its structure was established by X-ray analysis.Treatme

The preparation of 1-tributylstannyl glycals from 1-phenylsulfonyl glycals via Ni(0)-catalysed coupling with tributylstannylmagnesium bromide

1-Phenylsulfonyl glycals undergo an easy Ni(0)-catalysed coupling with tributylstannylmagnesium bromide to give the corresponding 1-tributylstannyl glycals in good yield.