22047-43-4Relevant articles and documents
Formation of persulphate from sodium sulphite and molecular oxygen catalysed by H5PV2Mo10O40-aerobic epoxidation and hydrolysis
Rubinstein, Amir,Carmeli, Raanan,Neumann, Ronny
, p. 13247 - 13249 (2015/05/20)
The H5PV2Mo10O40 polyoxometalate catalysed the electron transfer oxidation of sulphite to yield a sulphite radical, SO3- that upon addition of O2 yielded a peroxosulphate species efficient for the H5PV2Mo10O40 catalysed epoxidation of alkenes. The acidic polyoxometalate further catalysed hydrolysis of the epoxide to give vicinal diols in high yields. This journal is