220587-95-1

Basic information

• Product Name: (2R,3S,4R,5R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-(N',N'-diphenyl-hydrazino)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-ol
• Synonyms: (2R,3S,4R,5R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-(N',N'-diphenyl-hydrazino)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-ol
• CAS NO: 220587-95-1
• Molecular Weight: 670.921
• Mol File: 220587-95-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-(N',N'-diphenyl-hydrazino)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-(N',N'-diphenyl-hydrazino)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-ol(220587-95-1)
• EPA Substance Registry System: (2R,3S,4R,5R)-2-[(R)-2-(tert-Butyl-diphenyl-silanyloxy)-1-(N',N'-diphenyl-hydrazino)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-ol(220587-95-1)

Safety Data

• Hazardous Substances Data: 220587-95-1(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 38930-65-3 1,2-O-isopropylidene-3,5,6-tri-O-methyl-α-D-glucofuranose 
• 28436-51-3 3,5,6-tri-O-methyl-D-glucofuranose 
• 220587-67-7 phenyl 2-O-(diphenylhydrazono)acetyl-3,5,6-tri-O-methyl-1-seleno-β-D-glucofuranoside 
• 220587-80-4 3,6-anhydro-2-deoxy-2-(2,2-diphenylhydrazino)-5,7,8-tri-O-methyl-D-erythro-L-gulo-octono-1,4-lactone 
• 220587-93-9 phenyl 2-O-acetyl-3,5,6-tri-O-methyl-1-seleno-β-D-glucofuranoside 
• 220587-66-6 phenyl 3,5,6-tri-O-methyl-1-seleno-β-D-glucofuranoside 
• 728-15-4 (2,2-diphenylhydrazono)acetic acid 
• 530-47-2 N,N-diphenylhydrazine hydrochloride 

Downstream Products

• 220587-97-3 Benzoic acid (2R,3S,4S,5R)-2-[(R)-1-benzoylamino-2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-yl ester 
• 220587-99-5 Benzoic acid (2R,3S,4S,5R)-2-((R)-1-benzoylamino-2-hydroxy-ethyl)-5-((R)-1,2-dimethoxy-ethyl)-4-methoxy-tetrahydro-furan-3-yl ester 

Relevant articles and documents

Synthesis of C-glycosyl lactones and protected C-glycosyl amino acids: Use of radical cyclization

Protected carbohydrates 6a-13a, having one free hydroxyl and a phenylseleno group or halogen on the adjacent carbon, were condensed with (2,2-diphenylhydrazono)acetic acid (2); the resulting esters undergo radical cyclization to afford carbohydrates fused to a 2,2-diphenylhydrazino lactone unit (6c,d-13c,d). In suitable cases (9c,d) such carbohydrate lactones can be elaborated into C-glycosyl amino acids.