220625-83-2Relevant academic research and scientific papers
Rhenium complexes of 2-triorganosilylthiophenolato ligands. The syntheses and structures of [Bu4n(n)N][ReO(2-Ph3SiC6H4S)4] and [Re(2-Ph2MeSiC6H4S)3(MeZCN)(PPh3)]
Dilworth, J. R.,Lu, C.,Zheng, Y.,Zubieta, J.
, p. 501 - 510 (2008/10/08)
Reaction of the thiolates HSC6H4SiR3-2 (R3=Ph3, Ph2Me, PhMe2) with a range of Re precursors leads to the new complexes [ReH3(SC6H4SiPh2Me-2)2(PPh3)2], [ReO(SZC6H4SiPh2Me-2)3(PPh3)], Re(OMe)(SC6H4SiPh3-2)2(MeCN)(PPh3)] and [Re(SC6H4SiPh3-2)2(MeOH)(NO)(PPh3)]. The dependence of the producton the nature of the silyl substituents and the X-ray crystal structure s of [ReO(SC6H4SiPh3-2)4][Bu4(n)N]*Me2CO and [Re(SC6H4SiPh2Me-2)3(MeCN)(PPh3)] are discussed.
