220641-16-7Relevant academic research and scientific papers
Synthesis and Absolute Configuration of a Novel Aminoglycoglycerolipid, Species-Specific Major Immunodeterminant of Mycoplasma fermentans
Nishida, Yoshihiro,Takamori, Yusuke,Ohrui, Hiroshi,Ishizuka, Ineo,Matsuda, Kazuhiro,Kobayashi, Kazukiyo
, p. 2371 - 2374 (1999)
In order to determine the absolute configuration of a novel aminoglycoglycerolipid isolated from Mycoplasma fermentans, the possible two diastereomers were stereoselectively synthesized by using (S)- and (R)-glycidols as the key building block. Their 1H-1H-cosy spectra compared with those of the natural product allowed us to determine the absolute configuration of the glycolipid. - Keywords: amino-alcohols; glycolipids; immunodeficiency; phospholipids; phosphoramidites
Synthesis of plasmalogen via 2,3-Bis-O-(4′-methoxybenzyl)-sn-glycerol
Bittman, Robert,Byun, Hoe-Sup,Qin, Donghui
, p. 662 - 668 (2015/05/06)
The synthesis of the O-vinyl ether phospholipid plasmalogen 1 from 2,3-bis-O-[p-methoxybenzyl (PMB)]-sn-glycerol (13) is described. Treatment of 13 with potassium hydride, trichloroethylene, and n-butyllithium gave a 1-O-alkynyl glycerol derivative, which
