220649-22-9Relevant academic research and scientific papers
(Phosphacyclopentadienyl)indium(I) derivatives: Synthesis and X-ray crystal structure of [In(η5-P3C2But2)]
Callaghan, Charlotte,Clentsmith, Guy K. B.,Cloke, F. Geoffrey N.,Hitchcock, Peter B.,Nixon, John F.,Vickers, David M.
, p. 793 - 795 (2008/10/08)
Co-condensation of indium vapor and tert-butylphosphaethyne at 77 K yields two new, volatile In-(1) complexes: [In(η5-P3C2But2)] (1) and [In(η5-P2C3But3)] (2). A single-crystal X-ray diffraction experiment on 1 reveals a discrete molecular structure, involving half-sandwich coordination of the P3C2But2 ring around the indium center. 1 may be independently prepared by treating InI with the newly synthesized, base-free ligand salt K(P3C2But2).
