220823-62-1

Basic information

• Product Name: 1-(4-hydroxy-4-methylpentyl)cyclohexanol
• Synonyms: 1-(4-hydroxy-4-methylpentyl)cyclohexanol
• CAS NO: 220823-62-1
• Molecular Weight: 200.321
• Mol File: 220823-62-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(4-hydroxy-4-methylpentyl)cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-hydroxy-4-methylpentyl)cyclohexanol(220823-62-1)
• EPA Substance Registry System: 1-(4-hydroxy-4-methylpentyl)cyclohexanol(220823-62-1)

Safety Data

• Hazardous Substances Data: 220823-62-1(Hazardous Substances Data)

Upstream product

• 854712-92-8 5-(1-hydroxy-cyclohexyl)-2-methyl-pent-4-yn-2-ol 
• 408523-38-6 5-(1-hydroxy-cyclohexyl)-2-methyl-pent-3-yn-2-ol 
• 108-94-1 cyclohexanone 
• 67-64-1 acetone 
• 3384-04-1 3-chloropropyl phenyl ether 

Relevant articles and documents

3-chloropropyl and 4-chlorobutyl phenyl ethers as sources of 1,3-dilithiopropane and 1,4-dilithiobutane: Sequential reaction with carbonyl compounds

The reaction of 3-chloropropyl and 4-chlorobutyl phenyl ethers (1) with lithium powder and a catalytic amount of DTBB (5% molar) in THF at - 78 °C followed by successive treatment with a carbonyl compound [R1R2CO = ButCHO, Me2CO, (CH2)5CO, (-)-menthone] at -78 to 20 °C and, after 1.5 h at this temperature, with a second one [R3R4CO = Bu1CHO, PhCHO, Me2CO, MeCOPrn, (CH2)5CO, (-)-menthone] at -78 °C leads, after hydrolysis with water, to the corresponding 1,5-and 1,6-diols (2). Because of the competition of two different reductive cleavages, 1,4- and 1,5-diols 3 were also obtained as side-reaction products.