2209-36-1Relevant academic research and scientific papers
Copper(II)-mediated oxidation of 1,2-dioxime to furoxan
Das, Oindrila,Paria, Sayantan,Paine, Tapan Kanti
, p. 5924 - 5927 (2008)
1,2-Dioximes undergo oxidative transformation mediated by copper(II) ions in acetonitrile to form the corresponding furoxans in high yields. A series of 1,2-dioximes including aliphatic, aromatic, and heterocyclic dioximes were oxidized using these mild c
Oxidation of: O -dioxime by (diacetoxyiodo)benzene: Green and mild access to furoxans
He, Chunlin,Pang, Siping,Zhang, Qi,Zhang, Xun,Zhao, Cheng
supporting information, p. 1489 - 1493 (2022/01/31)
Furoxan has been widely used in the field of high energy density materials because of its excellent properties such as high density, high standard enthalpy of formation and high nitrogen content. However, its existing synthesis methods are still restricted by the problems of difficult substrate preparation and manual handling of hazardous reagents. Herein, we disclosed a mild oxidation strategy to efficiently obtain furoxan derivatives starting from readily available o-dioxime substrates. This reaction features high functional group tolerance and easy scale-up, and has excellent regioselectivity for specific nonsymmetric o-dioximes. This method greatly reduces the safety risk and simplifies the operation process, and means that diversified furoxan derivatives can be easily accessed, thus paving the way for the wide application of furoxan derivatives. This journal is
Synthesis method of furoxan compound
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Paragraph 0053-0060, (2021/01/04)
The invention discloses a synthesis method of a furazan oxide compound. The synthesis method comprises the following step of: oxidizing a glyoxime compound by taking iodobenzene diethyl ester as an oxidizing agent to carry out a reaction to obtain the fur
Alumina promoted cyclization of α-nitro-oximes: A new entry to the synthesis of 1,2,5-oxadiazoles N-oxides (furoxans)
Curini, Massimo,Epifano, Francesco,Marcotullio, Maria Carla,Rosati, Ornelio,Ballini, Roberto,Bosica, Giovanna
, p. 8817 - 8820 (2007/10/03)
A convenient method for the synthesis of 1,2,5-oxadiazole-N-oxides (furoxans) from α-nitro-ketoximes using acidic alumina as catalyst is described. (C) 2000 Elsevier Science Ltd.
