221004-76-8

Upstream product

• 221004-74-6 Acetic acid (3S,4S,7S,11R)-4-dibenzylamino-7-isobutyl-3-isopropyl-14-nitro-5,8-dioxo-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-11-yl ester 
• 87421-21-4 (2S,3S)-3-hydroxyleucine methyl ester 
• 10148-70-6 (2S,3S)-3-hydroxyleucine 
• 221004-69-9 (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid {(S)-1-[(R)-2-(4-fluoro-3-nitro-phenyl)-2-hydroxy-ethylcarbamoyl]-3-methyl-butyl}-amide 
• 221004-73-5 (3S,4S,7S,11R)-4-Dibenzylamino-11-hydroxy-7-isobutyl-3-isopropyl-14-nitro-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-triene-5,8-dione 
• 221004-75-7 Acetic acid (3S,4S,7S,11R)-4-dibenzylamino-7-isobutyl-3-isopropyl-5,8-dioxo-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-11-yl ester 
• 221004-70-2 (2S,3S)-2-Dibenzylamino-3-hydroxy-4-methyl-pentanoic acid pentafluorophenyl ester 
• 202478-35-1 (2S,3S)-N,N-dibenzyl hydroxyleucine 
• 17469-89-5 (2S)-2-(dimethylamino)-3-phenylpropanoic acid 
• 221004-68-8 Acetic acid (3S,4S,7S,11R)-4-amino-7-isobutyl-3-isopropyl-5,8-dioxo-2-oxa-6,9-diaza-bicyclo[10.2.2]hexadeca-1⁽¹⁵⁾,12⁽¹⁶⁾,13-trien-11-yl ester 
• 108-24-7 acetic anhydride 
• 107462-36-2 sanjoinine G₁ 

Downstream Products

• 107462-36-2 sanjoinine G₁ 

Relevant academic research and scientific papers

Absolute configuration of a cyclopeptide alkaloid, sanjoinine-G1, from Zizyphus vulgaris var. spinosus

A new cyclopeptide alkaloid, sanjoinine-G1, has been isolated from the seeds of Zizyphus vulgaris var. spinosus. The structure and absolute configuration has been established by spectroscopic analysis and the circular dichroism exiton-coupling method, as N-[(S)(N',N')-dimethylphenylalanyll- cyclo[O-(2S,3S)-β-oxyleucyl-(S)-leucyl-(2-mino-(1R)-hydroxyethyl)-p-phenyl].

A convergent approach to cyclopeptide alkaloids: Total synthesis of sanjoinine G1

A general strategy for the synthesis of cyclopeptide alkaloids containing an endocyclic aryl-alkyl ether bond has been developed featuring a key intramolecular SNAr reaction. The importance of the N-terminal protective group in the realization

An asymmetric total synthesis of sanjoinine G1

A convergent total synthesis of sanjoinine G1, a 14-membered cyclopeptide alkaloid was described. Formation of aryl-alkyl ether bond with concomitant construction of macrocycle by way of an intramolecular SNAr reaction was the key step in this synthesis.