221006-77-5Relevant academic research and scientific papers
Palladium-catalyzed synthesis and isolation of functionalized allylboronic acids: Selective, direct allylboration of ketones
Raducan, Mihai,Alam, Rauful,Szabo, Kalman J.
, (2012)
Allyl boronates are very important reagents in advanced organic synthesis for the allylation of carbonyl compounds[1] and in cross-coupling[2] reactions. A practically unrivalled property of allylboronates is their highly regio- and stereoselective additi
A one-pot "back-to-front" approach for the synthesis of benzene ring substituted indoles using allylboronic acids
Karan, Ganesh,Sahu, Samrat,Maji, Modhu Sudan
supporting information, p. 5274 - 5277 (2021/06/06)
Synthesis of only benzene ring functionalized indoles and poly-substituted carbazoles is reported via a one-pot triple cascade benzannulation protocol. Usage of differently substituted and readily accessible allylboronic acids as a 3-carbon annulating partner enables diverse aliphatic and aromatic substitution patterns, which is still a daunting task. This scalable synthetic protocol tolerates broad scope, thus enabling further downstream modifications. As an application, carbazole based natural products glycozoline and glycozolinol were synthesized. This journal is
