221098-03-9

Basic information

• Product Name: C₂₂H₃₂O₆Si
• Synonyms: C₂₂H₃₂O₆Si
• CAS NO: 221098-03-9
• Molecular Weight: 420.578
• Mol File: 221098-03-9.mol

Chemical Properties

• CAS DataBase Reference: C₂₂H₃₂O₆Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₂H₃₂O₆Si(221098-03-9)
• EPA Substance Registry System: C₂₂H₃₂O₆Si(221098-03-9)

Safety Data

• Hazardous Substances Data: 221098-03-9(Hazardous Substances Data)

Upstream product

• 5764-82-9 bromo(2-ethoxy-2-oxoethyl)zinc 
• 221098-01-7 C₂₀H₃₂O₆Si 

Relevant articles and documents

Studies toward the construction of the allyltrisulfide component in esperamicin-A1 from 5-ketoshikimic acid derivatives: Part 2

The MOM protected keto alcohol 7 was successfully converted to the silyl enol ether 4 by reaction with BSA. Reaction of this intermediate with dioxirane led to formation of allylic alcohol 10. Lactone 15 was obtained by reaction of tosylate 14 with the cuprate reagent derived from ethyl bromoacetate. Through a short sequence of reactions this 5-membered lactone was isomerized to the target lactone product 18.