5764-82-9Relevant articles and documents
The nature of the reformatsky reagent. Crystal structure of (BrZnCH2COO-t-Bu·THF)2
Dekker, Jan,Budzelaar, Peter H. M.,Boersma, Jaap,Van Der Kerk, Gerrit J. M.,Spek, Anthony L.
, p. 1403 - 1407 (1984)
The nature of the Reformatsky reagents derived from the ethyl and tert-butyl esters of bromoacetic acid has been studied by association measurements and NMR spectroscopy in various solvents. It appears that the reagents are dimeric in all but the most polar solvents. A dimeric structure containing both Zn-O and Zn-C single bonds is present in the crystalline state of (BrZnCH2COO-t-Bu·THF)2, the final X-ray analysis of which is reported. Crystals are monoclinic of space group P21/n with two dimers in a cell of dimensions a = 10.322 (3) A?, b = 12.358 (3) A?, c = 11.655 (2) A?, and β = 112.65 (2)°. The structure was refined to R = 0.055 on 881 observed reflections with I > 2.5σ(I). It is concluded that the dimeric structure found in the crystal persists in solution. In the very polar solvent Me2SO, the reagents are monomeric C-metalated species. The consequences of these findings for the mechanism of the Reformatsky reaction in the commonly used solvents are discussed.
Reactions of Alkyl 2-(Bromozinc)acylates with N-Chloro- and N-Bromodiethylamines
Zaynashev, A. T.,Zorin, А. V.,Zorin, V. V.
, p. 602 - 605 (2021/06/02)
Abstract: The reaction of alkyl 2-(bromozinc)acylates, obtained from ethyl bromoacetate (or butyl 2-bromobutanoate, or butyl 2-bromo-2-methylpropanoate) under the action of zinc, with N-chloro- or N-bromodiethylamine in tetrahydrofuran at 20–25°C under ar
COMPOUND, RESIN, RESIST COMPOSITION AND PRODUCTION METHOD OF RESIST PATTERN
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Paragraph 0223, (2020/10/27)
PROBLEM TO BE SOLVED: To provide a compound from which a resist pattern with good line edge roughness (LER) can be produced. SOLUTION: The compound is represented by formula (I). In the formula, R1 represents an alkyl group having 1 to 6 carbon atoms, H, or a halogen atom; X1 represents a connecting group such as -COO-C6H5-COO-; A1 represents a single bond or the like; A3 represents an alkanediyl group having 1 to 6 carbon atoms; W represents a divalent alicyclic hydrocarbon group having 3 to 18 carbon atoms; and R2 represents a substituted/unsubstituted hydrocarbon group having 1 to 28 carbon atoms. SELECTED DRAWING: None COPYRIGHT: (C)2021,JPO&INPIT