221101-09-3Relevant academic research and scientific papers
1,4 asymmetric induction in the carbonyl reduction of a γ- ketosulfoxide
Solladie, Guy,Colobert, Francoise,Somny, Frederic
, p. 1227 - 1228 (1999)
A chiral sulfoxide induced high stereoselectivity in the DIBAL-H reduction of a methyl ketone located in the γ position as a result of a 1,4- asymmetric induction. Addition of a lanthanide triflate or cerium chloride completely reversed the stereoselectiv
