22127-86-2

Basic information

• Product Name: 1-Undecyn-4-ol
• Synonyms: 1-Undecyn-4-ol
• CAS NO: 22127-86-2
• Molecular Formula: C₁₁H₂₀O
• Molecular Weight: 168.28
• Mol File: 22127-86-2.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 122-125 °C(Press: 17 Torr)
• Appearance: /
• Density: 0.877±0.06 g/cm3(Predicted)
• PKA: 14.32±0.20(Predicted)
• CAS DataBase Reference: 1-Undecyn-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Undecyn-4-ol(22127-86-2)
• EPA Substance Registry System: 1-Undecyn-4-ol(22127-86-2)

Safety Data

• Hazardous Substances Data: 22127-86-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 22, p. 1359, 1981 DOI: 10.1016/S0040-4039(01)90319-3

Upstream product

• 124-13-0 Octanal 
• 53915-69-8 allenyltributylstannane 
• 624-65-7 2-propynyl chloride 
• 106-96-7 propargyl bromide 

Downstream Products

• 104-67-6 5-heptyldihydro-2(3H)-furanone 

Relevant articles and documents

Catalytic propargylation of aldehydes with allenyltributylstannane by ytterbium triflate

The first ytterbium triflate [Yb(OTf)3]-catalyzed propargylation of various aldehydes with allenyltributylstannane to afford homopropargyl alcohols in good yields is described. The present result provides a versatile tool for preparation of an array of homopropargyl alcohols from the reaction of aldehydes with allenyltributylstannane; which are known to possess low reactivity.

Barbier-type allylation of carbonyl compounds and imines with metallic cadmium

Cadmium mediated allylation of a variety of carbonyl compounds and imines in a Cd/Bu4NBr/THF system afforded excellent yields of the corresponding homoallylic alcohols and amines under very mild reaction conditions.

Indium in Organic Synthesis: Indium-Mediated Allylation of Carbonyl Compounds

Indium-mediated allylation of a variety of ketones and aldehydes afforded excellent yields of the corresponding homoallylic alcohols under very mild reaction conditions.