221290-72-8

Basic information

• Product Name: {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol
• Synonyms: {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol
• CAS NO: 221290-72-8
• Molecular Weight: 312.45
• Mol File: 221290-72-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol(221290-72-8)
• EPA Substance Registry System: {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol(221290-72-8)

Safety Data

• Hazardous Substances Data: 221290-72-8(Hazardous Substances Data)

Upstream product

• 33375-08-5 (R)-5-isopropyl-2-methylcyclohex-2-enone 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 380414-34-6 (E)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-enoic acid 
• 221290-56-8 [(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-acetic acid 
• 380414-42-6 2-((1R,5R,6R)-6-Dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl)-ethanol 
• 221290-71-7 acetic acid (1S,4R,5R)-4-dimethoxymethyl-5-isopropyl-2-methylcyclohex-2-enyl ester 
• 221290-57-9 [(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-acetaldehyde 
• 221290-54-6 (4R,5R)-4-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enone 
• 221290-59-1 (E)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-en-1-ol 
• 291520-38-2 (4R,5R)-5-Dimethoxymethyl-4-isopropyl-1-methyl-6-methylene-cyclohexene 
• 291520-37-1 1-methyl-(4S)-isopropyl-(5R)-dimethyl acetal-1-cyclohexen-6-one 

Downstream Products

• 380414-35-7 (2S,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxirane-2-carbaldehyde 
• 221290-75-1 (Z)-{(5S)-5-[(1R)-2-((1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl)-1-hydroxyethyl]-5-methyl-5H-furan-2-ylidene}-acetic acid ethyl ester 

Relevant articles and documents

Synthetic studies on the sarcodictyins: Synthesis of fully functionalized cyclization precursors

A strategy featuring a key retrosynthetic disconnection at the C2-C3 position was applied to the total synthesis of the common diterpenoid tricyclic skeleton of sarcodictyins and eleutherobin. Fully functionalized cyclization precursors were accessed via a brief and convergent route, making use of unprecedented synthetic transformations.

Synthetic studies on sarcodictyins and eleutherobin: Synthesis of fully functionalized cyclization precursors

Unprecedented synthetic transformations were demonstrated during the preparation of fully functionalized cyclization precursors of type 2, in a synthetic approach to sarcodictyin A and B (1a,b) and eleutherobin (1c).