221290-57-9

Upstream product

• 33375-08-5 (R)-5-isopropyl-2-methylcyclohex-2-enone 
• 221290-56-8 [(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-acetic acid 
• 221290-71-7 acetic acid (1S,4R,5R)-4-dimethoxymethyl-5-isopropyl-2-methylcyclohex-2-enyl ester 
• 221290-55-7 (1S,4R,5R)-4-dimethoxymethyl-5-isopropyl-2-methylcyclohex-2-enol 
• 221290-54-6 (4R,5R)-4-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enone 
• 380414-42-6 2-((1R,5R,6R)-6-Dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl)-ethanol 

Downstream Products

• 380414-33-5 (Z)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-enoic acid 
• 380414-34-6 (E)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-enoic acid 
• 402827-26-3 (2R)-1-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methylcyclohex-2-enyl]pent-4-en-2-ol 
• 380414-35-7 (2S,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxirane-2-carbaldehyde 
• 221290-58-0 (Z)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-en-1-ol 
• 221290-59-1 (E)-4-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl]-2-methyl-but-2-en-1-ol 
• 221290-60-4 {(2R,3S)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol 
• 221290-61-5 {(2S,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol 
• 221290-72-8 {(2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxiranyl}-methanol 
• 221290-75-1 (Z)-{(5S)-5-[(1R)-2-((1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enyl)-1-hydroxyethyl]-5-methyl-5H-furan-2-ylidene}-acetic acid ethyl ester 
• 221290-74-0 (2R,3R)-3-[(1R,5R,6R)-6-dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl]-2-methyl-oxirane-2-carbaldehyde 
• 221290-62-6 (2S,3S)-3-((1R,5R,6R)-6-Dimethoxymethyl-5-isopropyl-2-methyl-cyclohex-2-enylmethyl)-2-methyl-oxirane-2-carbaldehyde 
• 639056-22-7 2,2-dimethylpropionic acid (4R,4aR,6R,7R,11R,12aR)-11-(tert-butyl(diphenyl)silanyloxy)-4-isopropyl-1-methyl-7-[tetrahydropyran-2'-yloxy]-3,4,4a,5,6,7,10,11,12,12a-decahydrobenzocyclodecen-6-yl ester 
• 503071-81-6 2,2-dimethylpropionic acid (4R,4aR,6S,7S,11R,12aR)-11-(tert-butyl(diphenyl)silanyloxy)-4-isopropyl-1-methyl-7-[(2'RS)-tetrahydropyran-2'-yloxy]-3,4,4a,5,6,7,10,11,12,12a-decahydrobenzocyclodecen-6-yl ester 

Relevant academic research and scientific papers

Synthetic studies on the sarcodictyins: Synthesis of fully functionalized cyclization precursors

A strategy featuring a key retrosynthetic disconnection at the C2-C3 position was applied to the total synthesis of the common diterpenoid tricyclic skeleton of sarcodictyins and eleutherobin. Fully functionalized cyclization precursors were accessed via a brief and convergent route, making use of unprecedented synthetic transformations.

Synthetic studies on sarcodictyins and eleutherobin: Synthesis of fully functionalized cyclization precursors

Unprecedented synthetic transformations were demonstrated during the preparation of fully functionalized cyclization precursors of type 2, in a synthetic approach to sarcodictyin A and B (1a,b) and eleutherobin (1c).