221292-41-7Relevant academic research and scientific papers
Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin
Kolivo?ka,Mohos,Pobelov,Rohrbach,Yoshida,Hong,Fu,Moreno-García,Mészáros,Broekmann,Hromadová,Sokolová,Valá?ek,Wandlowski, Th.
supporting information, p. 11757 - 11759 (2015/05/20)
The forces required for the detachment of ferrocene (Fc) from β-cyclodextrin (βCD) in a single host (βCD)-guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex. This journal is
Synthesis and testing of new end-functionalized oligomers for molecular electronics
Flatt, Austen K.,Dirk, Shawn M.,Henderson, Jay C.,Shen, Dwanleen E.,Su, Jie,Reed, Mark A.,Tour, James M.
, p. 8555 - 8570 (2007/10/03)
Several new classes of oligomers have been synthesized with functionalities designed to aid in the understanding of molecular device behavior, specifically when molecules are interfaced between proximal electronic probes. The compounds synthesized are series of azobenzenes, bipyridines and oligo(phenylene vinylene)s that bear acetyl-protected thiols for ultimate attachment to metallic surfaces. Some initial electrochemical and solid-state test results are also reported.
Soluble ferrocene conjugates for incorporation into self-assembled monolayers
Yu,Chong, Yoochul,Kayyem, Jon Faiz,Gozin, Michael
, p. 2070 - 2079 (2007/10/03)
A series of phenylethynyl oligomers (I-V) possessing a ferrocene and thiol at each termini have been synthesized. These oligomers have been designed to overcome the inherent insolubility of this class of complexes by substitution at the phenyl groups with methyl and propoxy substituents. Several new reactions for preparing arenethiol-protected compounds are described. Interestingly, the generation of an arenethiol anion during base- or fluoride-catalyzed deprotection has been characterized.
