221292-47-3

Basic information

• Product Name: ((4-bromo-2-methylphenyl)ethynyl)trimethylsilane
• Synonyms: ((4-bromo-2-methylphenyl)ethynyl)trimethylsilane
• CAS NO: 221292-47-3
• Molecular Weight: 267.241
• Mol File: 221292-47-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ((4-bromo-2-methylphenyl)ethynyl)trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: ((4-bromo-2-methylphenyl)ethynyl)trimethylsilane(221292-47-3)
• EPA Substance Registry System: ((4-bromo-2-methylphenyl)ethynyl)trimethylsilane(221292-47-3)

Safety Data

• Hazardous Substances Data: 221292-47-3(Hazardous Substances Data)

Upstream product

• 116632-39-4 2-methyl-4-bromoiodobenzene 
• 1066-54-2 trimethylsilylacetylene 
• 591-17-3 meta-bromotoluene 

Downstream Products

• 1257102-57-0 2,2'-dimethyl-4,4'-dibromotolane 
• 1312479-78-9 4-bromo-1-ethynyl-2-methylbenzene 
• 221292-56-4 4-(2-{4-[4-(4-iodo-phenylethynyl)-3-methyl-phenylethynyl]-phenylsulfanyl}-ethyl)-pyridine 
• 221292-53-1 4-{4-[2-(tert-Butyl-dimethyl-silanyl)-ethylsulfanyl]-phenylethynyl}-2-methyl-1-trimethylsilanylethynyl-benzene 
• 221292-52-0 2-Methyl-4-[4-(2-trimethylsilanyl-ethylsulfanyl)-phenylethynyl]-1-trimethylsilanylethynyl-benzene 
• 207724-70-7 4-{2-[4-(3-methyl-4-trimethylsilanylethynyl-phenylethynyl)-phenylsulfanyl]-ethyl}-pyridine 
• 221292-55-3 tert-butyl-{2-[4-(4-ethynyl-3-methyl-phenylethynyl)-phenylsulfanyl]-ethyl}-dimethyl-silane 
• 221292-54-2 4-ethynyl-3-methyl-{[4-(2-(trimethylsilyl)ethyl)sulfanyl]phenylethynyl}benzene 
• 207724-69-4 4-{2-[4-(4-ethynyl-3-methyl-phenylethynyl)-phenylsulfanyl]-ethyl}-pyridine 
• 207724-68-3 2-(trimethylsilyl)ethynyl-5-iodotoluene 

Relevant articles and documents

Synthesis and Delayed Fluorescent Properties of p-Nido-Carborane-Triarylborane Conjugates with a Methyl-Substituted Phenylene Linker

A series of p-nido-carborane-triarylborane conjugates (nido-1-3) in which a methyl group is introduced at the ortho-position to the carborane cage in the phenylene linker was prepared and characterized. All compounds exhibit broad low-energy absorptions (

Photochemical behavior of (diphosphine)(η2-tolane)Pt 0 complexes. Part A: Experimental considerations in solution and in the solid state

A series of various (diphosphine)(η2-tolane)Pt0 complexes exhibiting manifold substitution pattern of the tolane ligand (5a-g) and different rigid diphosphines defining various bite angles at the Pt center (9a-b) have been synthesized. All compounds were isolated and characterized by means of spectroscopic methods and additionally by X-ray structure determination (5a-e, 9a-b). In view of potential Caryl-Cethynyl bond activation, we investigated their photochemical behavior in the solid state as well as in solution by irradiating with sunlight. The reactivity towards C aryl-Cethynyl bond activation in the crystalline state and in solution is discussed in relation to substituents attached to the tolane ligand and on the extent of the torsion of its phenyl rings. Complexes 5a-c and 9a either bearing electron withdrawing bromides or possessing a large dihedral angle of the phenyl rings, showed selective oxidative addition of the C aryl-Cethynyl bond to the Pt center in the solid state, yielding complexes 6a-c and 10a, respectively. In contrast, 5d-f and 9b proved to be unreactive under similar conditions because of their electron donating methoxy groups as well as the reduced twisting of their phenyl or pyridyl moieties of the tolane ligands. Irradiation of complexes 5a and 5b with sunlight in solution revealed the formation of the appropriate C-Br activated compounds 7a and 7b along with 6a and 6b in a 1:1 mixture. The observed photochemical Caryl-Cethynyl bond activation is reversible under thermal conditions, regaining the appropriate Pt0 complexes by reductive elimination.