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221325-43-5

N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 221325-43-5 Structure

  • Basic information

    1. Product Name: N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester
    2. Synonyms: N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester
    3. CAS NO:221325-43-5
    4. Molecular Formula:
    5. Molecular Weight: 558.75
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 221325-43-5.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester(221325-43-5)
    11. EPA Substance Registry System: N-(9-fluorenylmethoxycarbonyl)-O-[(4-amino-α,α-dimethylbenzyl)dimethylsilyl]-L-serine allyl ester(221325-43-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 221325-43-5(Hazardous Substances Data)

221325-43-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 221325-43-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,1,3,2 and 5 respectively; the second part has 2 digits, 4 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 221325-43:
(8*2)+(7*2)+(6*1)+(5*3)+(4*2)+(3*5)+(2*4)+(1*3)=85
85 % 10 = 5
So 221325-43-5 is a valid CAS Registry Number.

221325-43-5Relevant articles and documents

A novel silyl linker: Motif for side chain tethered approach to solid- phase glycopeptide synthesis

Nakamura, Kazuhiko,Ishii, Akira,Ito, Yukishige,Nakahara, Yoshiaki

, p. 11253 - 11266 (2007/10/03)

In order to facilitate the solid-phase syntheses of protected glycopeptide blocks, we designed a novel silyl linker, which allows the alcoholic side chain (carbohydrate, serine, or threonine) of (glyco-)peptides to link to the solid support. Utilizing this linker, peptide coupling reactions at both the N- and the C-termini were successful. Synthesis of the glycophorin AM fragment corresponding to the N-terminal glycoheptapeptide is demonstrated.

Design and synthesis of silyl ether-based linker for solid-phase synthesis of glycopeptides

Nakamura, Kazuhiko,Hanai, Noriyasu,Kanno, Masayuki,Kobayashi, Aki,Ohnishi, Yuki,Ito, Yukishige,Nakahara, Yoshiaki

, p. 515 - 518 (2007/10/03)

A novel silyl linker was designed to facilitate the solid-phase synthesis of protected glycopeptide blocks. Alcohols (carbohydrate, serine, or threonine) were silylated with trialkylchlorosilane containing the p- nitrophenyl group. The nitro group was reduced and succinylated to give the succinanilic acids, which were attached to the glycine-preloaded resin via activation with HBTU/HOBt. After elongation of the peptide chain by segment condensation of Fmoc chemistry-based stepwise method, the synthesized glycopeptides in the protected form were split from the resin by fluoridolysis.

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